CBSE Class 11 Chemistry Chapter 2 Structure of The Atom Study Materials

Subtopics Of Class 11 Chemistry Chapter 2 Structure Of The Atom

  1. Sub-atomic Particles
    • Discovery Of Electron
    • Charge To Mass Ratio Of Electron
    • Charge On The Electron
    • Discovery Of Protons And Neutrons
  2. Atomic Models
    • Thomson Model Of Atom
    • Rutherford’s Nuclear Model Of Atom
    • Atomic Number And Mass Number
    • Isobars And Isotopes
    • Drawbacks Of Rutherford Model
  3. Developments Leading To The Bohr’s Model Of Atom
    • Wave Nature Of Electromagnetic Radiation
    • Particle Nature Of Electromagnetic Radiation: Planck’s Quantum Theory
    • Evidence For The Quantized* Electronic Energy Levels: Atomic Spectra
  4. Bohr’s Model For Hydrogen Atom
    • Explanation Of Line Spectrum Of Hydrogen
    • Limitations Of Bohr’s Model
  5. Towards Quantum Mechanical Model Of The Atom
    • Dual Behaviour Of Matter
    • Heisenberg’s Uncertainty Principle
  6. Quantum Mechanical Model Of Atom
    • Orbitals And Quantum Numbers
    • Shapes Of Atomic Orbitals
    • Energies Of Orbitals
    • Filling Of Orbitals In Atom
    • Electronic Configuration Of Atoms
    • Stability Of Completely Filled And Half Filled Subshells.

Structure of Atom Class 11 Notes Chemistry Chapter 2

Introduction


In the previous chapter, we have discussed about Some Basic Concept of Chemistry but in this chapter, we shall study about Structure of Atom. Atom is made up of still smaller particles like electrons, protons and neutrons. The arrangement of these particles within the atom was put forward by Rutherford (in 1911) on the basis of his “Scattering experiments“.

The word “atom” has been derived from the Greek word ‘atoms’ which mans ‘indivisible’. These early ideas were mere speculation and there was no way to test them experimentally.

Atomic Structure


Atom is made up of smaller units like proton, neutron and electron. Some other particles like positron, neutrino, antineutrino, π-meson, μ-meson, k meson etc are also present which are very short lived.

Structure of Atom Class 11 Notes

Discovery of Electron

In 1879, William Crooks studied the conduction of electricity through gases at low pressure. He performed the experiment in a discharge tube which is a cylindrical hard glass tube about 60 cm in length. It is sealed at both the ends and fitted with two metal electrodes. The electrical discharge through the gases could be observed only at very low pressures and at very high voltages.

Structure of Atom Class 11 Notes

J.J. Thomson took a discharge tube and applied a voltage of a 10000 volt potential difference across it at a pressure of 10–2 mm of Hg. He found some glowing behind anode. It means some invisible rays produced at cathode strike behind anode and produce fluorescence. He named them cathode rays.

Properties of Cathode Rays

  1. These rays have mechanical energy and travel in straight line.
  2. These rays are deflected towards positive plate of electric field. It means these are made up of negatively charged particle called electron.
  3. Colour observed is independent from nature of gas.
  4. Mulliken determined the charge on electron which is 1.602 × 10–19 C.
  5. Specific charge on electron is calculated by J.J. Thomson.

Charge to mass ratio

J.J. Thomson for the first time experimentally determined charge/mass ratio called e/m ratio for the electrons. For this, he subjected the beam of electrons released in the discharge tube as cathode rays to influence the electric and magnetic fields. These were acting perpendicular to one another as well as to the path followed by electrons.

According to Thomson, the amount of deviation of the particles from their path in presence of electrical and magnetic field depends on

  1. Magnitude of the negative charge on particle
  2. Mass of particle
  3. Strength of magnetic field
Structure of Atom Class 11 Notes

When electric field is applied, deviation from path takes place. If only electric field is applied, cathode rays strike at A. If only magnetic field is applied, cathode rays strike at C. In absence of any field, cathode rays strike at B.

By carrying out accurate measurements on the amount of deflections observed by the electrons on the electric field strength or magnetic field strength, Thomson was able to determine the value of

e/me = 1.758820 x 1011 C kg-1 

where me = Mass of the electron in kg

e = magnitude of charge on the electron in coulomb (C).

Discovery of anode rays

In 1886, Goldstein modified the discharge tube by using a perforated cathode. On reducing the pressure, he observed a new type of luminous rays passing through the holes or perforations of the cathode and moving in a direction opposite to the cathode rays. These rays were named as positive rays or anode rays or as canal rays. Anode rays are not emitted from the anode but from a space between anode and cathode.

Properties of anode rays

  1. These rays deflect towards negative plate of applied electric field. It means these are made up of positively charged particle.
  2. Property of anode rays depends on nature of gas.
  3. These rays travel in straight line and have mechanical energy.

Discovery of Neutron

Chadwick in 1932 found the evidence for the production of neutron in given reaction.

4Be9 + 2He46C12 + 0n1

Neutron is chargeless particle and have mass equal to proton.

Millikan’s Oil Drop Experiment

In this experiment, some fine oil droplets were allowed to enter through a tiny hole into the upper plate of electrical condenser. These oil droplets were produced by atomiser. The air in the chamber was subjected to the ionization by X-rays. The electrons produced by the ionization of air attach themselves to the oil drops.

Structure of Atom Class 11 Notes

Thus oil droplets acquire negative charge. When sufficient amount of electric field is applied, the motion of the droplets can be accelerated, retarded or made stationary. Millikan observed that the smallest charge found on them was –1.6 × 10–19 coulomb and the magnitude of electrical charge, q on the droplets is always an integral multiple of the electrical charge ‘e’ i.e., q = ne

Thomson’s Model of Atom

J.J. Thomson in 1898, proposed a model of atom which looked more or less like plum pudding or raisin pudding. He assumed atom to be a spherical body in which electrons are unevenly distributed in a sphere having positive charge which balance the electron’s charge. It is called Plum pudding model.

Structure of Atom Class 11 Notes

Important Feature of This Model : The mass of the atom is assumed to be uniformly distributed over whole atom.

Failure : This model was able to explain the overall neutrality of the atom, it could not satisfactorily, explain the results of scattering experiments carried out by Rutherford in 1911.

Rutherford’s Model

Rutherford in 1911, performed some scattering experiments in which he bombarded thin foils of metals like gold, silver, platinum or copper with a beam of fast moving a-particles. The thin gold foil had a circular fluorescent zinc sulphide screen around it. Whenever a-particles struck the screen, a tiny flash of light was produced at that point.

Structure of Atom Class 11 Notes

From these experiments, he made the following observations:

  1. Most of the α-particles pass without any deviation.
  2. Few particles deviate with small angle.
  3. Rare particles retrace its path or show deflection greater than 90°.
Structure of Atom Class 11 Notes

On the basis of these observation, he proposed a model.

  1. Atom is of spherical shape having size of order 10–10 meters.
  2. Whole mass is concentrated in centre called nucleus having size of order 10–15 meters.
  3. Electron revolves around the nucleus in circular path like planets revolve around sun.

Limitation : This model could not explain stability of atom. According to Maxwell’s classic theory, an accelerated charged particle liberates energy. So, during revolution, it must radiate energy and by following the spiral path it should comes on nucleus.

Atomic number

It is equal to the number of protons present in the nucleus of an atom. Atomic number is designated by the letter ‘Z’. In case of neutral atom atomic number is equal to the number of protons and even equal to the number of electrons in atom.

Z = Number of protons (p) = Number of electrons (e)

Mass number

It is equal to the sum of the positively charged protons (p) and electrically neutral neutrons (n). Mass number of an atom is designated by the letter ‘A’.

Mass number (A) = Number of protons (p or Z) + Number of neutrons (n)

Note : The atom of an element X having mass number (A) and atomic number (Z) may be represented by a symbol ZXA.

Isotopes

Atoms with identical atomic number but different atomic mass number are known as Isotopes. Isotopes of Hydrogen 1H1, 1H2 and 1H3

Isobars

Isobars are the atom with the same mass number but different atomic number, for example 6C14 and 7N14

Electromagnetic Waves Theory


This theory was put forward by James Clark Maxwell in 1864. Electromagnetic Waves are the waves which are produced by varying electric field and magnetic field which are perpendicular to each other in the direction perpendicular to both of them.

Structure of Atom Class 11 Notes

The main points of this theory are as follows:

  1. The energy is emitted from any source continuously in the form of radiations and is called the radiant energy.
  2. The radiations consist of electric and magnetic fields oscillating perpendicular to each other and both perpendicular to the direction of propagation of the radiation.
  3. The radiations possess wave character and travel with the velocity of light 3 x 108 m/sec.
  4. These waves do not require any material medium for propagation. For example, rays from the sun reach us through space which is a non-material medium.

Characteristics of a Wave

Wavelength (λ) : It is the distance between two consecutive crests or troughs and is denoted by λ.

Frequency (v) : It is the number of waves passing through a given point in one second. The unit frequency is hertz or cycle per second.

Wave number : It is the number of waves in a unit cycle. wave number `=\frac{1}{λ}`

Velocity : Velocity of a wave is defined as the linear distance travelled by the wave in one second. It is represented by c and is expressed in m/sec.

Amplitude : Amplitude of a wave is the height of the crest or the depth of the through. It is represented by V and is expressed in the units of length.

Black Body Radiations

Black-body is an ideal body which emits and absorbs radiations of all frequencies. The radiation emitted by these bodies is called black-body radiation.

Structure of Atom Class 11 Notes

At a given temperature, the intensity and frequency of the emitted radiation depends is temperature. At a given temperature, the intensity of radiation emitted increases with decrease of wavelength.

Photoelectric Effect

When light of a suitable frequency is allowed to incident on a metal, ejection of electrons take place. This phenomenon is known as photo electric effect.

Structure of Atom Class 11 Notes

Observations in Photoelectric Effect

  1. Only photons of light of certain minimum frequency called threshold frequency (v0) can cause the photoelectric effect. The value of v0 is different for different metals.
  2. The kinetic energy of the electrons which are emitted is directly proportional to the frequency of the striking photons and is quite independent of their intensity.
  3. The number of electrons that are ejected per second from the metal surface depends upon the intensity of the striking photons or radiations and not upon their frequency.

Explanation of Photoelectric Effect

Einstein in (1905) was able to give an explanation of the different points of the photoelectric effect using Planck’s quantum theory as under:

  1. Photoelectrons are ejected only when the incident light has a certain minimum frequency (threshold frequency v0).
  2. If the frequency of the incident light (v) is more than the threshold frequency (v0), the excess energy (hv–hv0) is imparted to the electron as kinetic energy.
  3. On increasing the intensity of light, more electrons are ejected but the energies of the electrons are not altered.

K.E. of the ejected electron.

`\frac{1}{2}mv^{2}=hv–hv_{0}`

Planck’s Theory


According to this theory, energy cannot be absorbed or released continuously but it is emitted or released in the form of small packets called quanta. In case of light this quanta is known as photon. This photon travels with speed of light. Energy of the photon is directly proportional to frequency.

`E\propto\nu`

`E=h\nu`

h is Planck’s constant, value is 6.62 × 10–34 Js

Bohr’s Model


Niels Bohr in 1913, proposed a new model of atom on the basis of Planck’s Quantum Theory. The main points of this model are as follows:

  1. Atom is of spherical shape having size (of order 10–10 metre).
  2. Whole mass is concentrated in centre called nucleus (having order of size 10–15 metre).
  3. Electron revolves around nucleus only in limited circular path and he assumed that electron does not radiate energy during its revolution in permitted paths.
  4. Only those orbits are allowed whose orbit angular momentum is integral multiple of `h/{2\pi}`.

    `mvr=frac{nh}{2\pi}`, where n = 1, 2, 3, 4…

  5. When electron absorbs energy, it jumps to higher orbit and when it comes back, it radiates energy. This postulate explain spectra.

Achievements of Bohr’s Theory

  1. Bohr’s theory has explained the stability of an atom.
  2. Bohr’s theory has helped in calculating the energy of electron in hydrogen atom and one electron species.
  3. Bohr’s theory has explained the atomic spectrum of hydrogen atom.

Limitations of Bohr’s Model

  1. The theory could not explain the atomic spectra of the atoms containing more than one electron or multielectron atoms.
  2. Bohr’s theory failed to explain the fine structure of the spectral lines.
  3. Bohr’s theory could not offer any satisfactory explanation of Zeeman effect and Stark effect.
  4. Bohr’s theory failed to explain the ability of atoms to form molecule formed by chemical bonds.
  5. It was not in accordance with the Heisenberg’s uncertainty principle.

Spectra


The most compelling evidence for the quantization of energy comes from spectroscopy. Spectrum word is taken from Latin word which means appearance. The record of the intensity transmitted or scattered by a molecule as a function of frequency or wavelength is called its spectrum.

Structure of Atom Class 11 Notes

Cosmic rays < gamma rays < x rays < ultraviolet rays < visible rays < infra red < micro waves < radio waves

Line Spectrum of Hydrogen Atom


When electric discharge is passed through hydrogen gas enclosed in discharge tube under low pressure and the emitted light is analysed by a spectroscope, the spectrum consists of a large number of lines which are grouped into different series. The complete spectrum is known as hydrogen spectrum.

On the basis of experimental observations, Johannes Rydberg noted that all series of lines in the hydrogen spectrum could be described by the following expression:

wave number = `\frac{1}{\lambda}=R(\frac{1}{n_{1}^{2}}-frac{1}{n_{2}^{2}})`

R = Rydberg constant

R = 109678 cm–1

Structure of Atom Class 11 Notes
Structure of Atom Class 11 Notes

Zeeman Effect

When spectral line (source) is placed in magnetic field, spectral lines split up into sublines. This is known as zeeman effect.

Stark Effect

If splitting of spectral lines take place in electric field, then it is known as stark effect.

Dual Behaviour of Matter (de Broglie Equation)

de Broglie in 1924, proposed that matter, like radiation, should also exhibit dual behaviour i.e., both particle like and wave like properties. This means that like photons, electrons also have momentum as well as wavelength.

Assume light have wave nature, then its energy should be given by Planck’s theory

`E=h\nu` …(i)

If it have particle nature, then its energy should be given by Einstein relation

E = mc2 …(ii)

On comparing equation (i) and (ii),

`h\nu=mc^2`

`\lambda=h/{mc}` (for light) …(iii)

For other matter,

`\lambda=h/{mv}` …(iv)

`\lambda=h/p` …(v)

where p = momentum

This equation is called de Broglie equation.

Heisenberg’s Uncertainty Principle


It states that, “It is impossible to measure simultaneously the exact position and exact momentum of a microscopic particle”.

If uncertainty in position = Δx and

Uncertainty in momentum = ΔP

When both are measured simultaneously, According to this principle,

`Δx.ΔP\geq\frac{h}{4\pi}`

Quantum Numbers


There are a set of four quantum numbers which specify the energy, size, shape and orientation of an orbital. To specify an orbital only three quantum numbers are required while to specify an electron all four quantum numbers are required.

(i). Principal quantum number (n)

It identifies shell, determines sizes and energy of orbitals. It is indicated by ‘n’ and its values are 1, 2, 3, 4…

(ii). Azimuthal quantum number (l)

Azimuthal quantum number. ‘l’ is also known as orbital angular momentum or subsidiary quantum number. l. It identifies sub-shell, determines the shape of orbitals, energy of orbitals in multi-electron atoms along with principal quantum number and orbital angular momentum, i.e., The number of orbitals in a sub shell = 2l + 1. For a given value of n, it can have n values ranging from 0 to n-1.

(iii). Magnetic quantum number (ml)

It gives information about the spatial orientation of the orbital with respect to standard set of co-ordinate axis.For any sub-shell (defined by ‘l’ value) 2l+1 values of ml are possible. For each value of l, ml = – l, – (l–1), – (l–2)… 0,1…(l–2), (l–1), l

Electron spin quantum number (ms)

It refers to orientation of the spin of the electron. It can have two values +1/2 and -1/2. +1/2 identifies the clockwise spin and -1/2 identifies the anti-clockwise spin.

Shape of Atomic Orbitals


(i). Shapes of s-orbitals

s-orbital is present in the s-sub shell. For this sub shell, l = 0 and ml = 0. Thus, s-orbital with only one orientation has a spherical shape with uniform electron density along all the three axes. The probability of Is electron is found to be maximum near the nucleus and decreases with the increase in the distance from the nucleus.

Structure of Atom Class 11 Notes

(ii). Shapes of p-orbitals

p-orbitals are present in the p-subshell for which l = 1 and ml can have three possible orientations –1, 0, +1. Thus, there are three orbitals in the p-subshell which are designated as px, py and pz orbitals depending upon the axis along which they are directed. The general shape of a p-orbital is dumb-bell consisting of two portions known as lobes.

Structure of Atom Class 11 Notes

(iii). Shapes of d-orbitals

d-orbitals are present in d-subshell for which l = 2 and ml = -2, -1, 0, +1 and +2. This means that there are five orientations leading to five different orbitals. d orbitals are of five types :dxy, dyz, dzx, dx2-y2, dz2

Structure of Atom Class 11 Notes

Electronic Configuration


Distribution of electron in various orbitals is known as electronic configuration. The electrons filled in orbitals must obey the following rules –

  1. Aufbau’s principle
  2. Pauli’s exclusion principle
  3. Hund’s rule of maximum multiplicity

(i). Aufbau’s principle

According to this principle, orbitals with lowest energy are filled before the orbitals having higher energy.

Structure of Atom Class 11 Notes

1s < 2s < 2p < 3s < 3p < 4s < 3d < 4p < 5s < 4d < 5p < 6s < 4f < 5d < 6p < 7s < 5f < 6d < 7p

(n + l) rule (Bohr Bury’s Rule)

According to this, The orbital which has lower value of (n + l) is lower in energy.

(ii). Pauli’s exclusion principle

According to this principle, in an atom, no two electrons have same value of all the four quantum numbers. In the same orbital, electron always accommodate in opposite spins. An orbital can have a maximum of two electrons, with opposite spin.

(iii). Hund’s rule of maximum multiplicity

According to this rule, electrons are distributed among the orbital of a subshell in such a way so as to give the maximum number of unpaired electrons with a parallel spin.

Structure of Atom Class 11 Notes

Summary


  1. Atomic number : It is equal to the number of protons in the nucleus of an atom. 
  2. Mass number : It is equal to the sum of the positively charged protons (p) and electrically neutral neutrons (n).
  3.  Isotopes : Isotopes are the atoms of the same element which have the same atomic number but different mass numbers.
  4. Isobars are the atoms of different elements having the same mass number but different atomic numbers.
  5. Isoelectronic species : These are those species which have same number of electrons.
  6. Radiations : These are defined as the emission or transmission of energy through space in the form of waves.
  7. Electromagnetic waves : The waves which consist of oscillating electric and magnetic fields are called electromagnetic waves.
  8. Electromagnetic radiations : Those radiations which are associated with electric and magnetic field are called electromagnetic radiations.
  9. Electromagnetic spectrum : The arrangement of the various types of electromagnetic radiations in the order of increasing or decreasing wavelengths or frequencies is known as electromagnetic spectrum.
  10. Wavelength (λ) : It is the distance between successive points of equal phase of a wave.
  11. Frequency (f) : The number of waves that pass a given point in one second is known as the frequency.
  12. Time period (T) : Time taken by the wave for one complete cycle or vibration is called time period.
  13. Velocity (v) : It is the distance travelled by a wave in one second.
  14. Wave number : It is defined as the number of wavelengths per unit length.
  15. Threshold frequency : It is the minimum frequency of light needed to cause the photoelectric effect.
  16. Continuous spectrum : The combination of light of different frequencies in continuous manner is called continuous spectrum.
  17. Line spectrum : The spectrum of atoms consist of sharp well-defined lines corresponding to definite frequencies is called line spectrum.
  18. Spectroscopy : The study of emission or absorption spectra is called spectroscopy.
  19. Quantization : The restriction of a property to discrete values and not continuous values is called quantization.
  20. Quantum mechanics : The branch of science that takes into account the dual behaviour of matter is called quantum mechanics.
  21. Atomic orbital : It is the region of space where the probability of finding the electron is maximum.
  22. Quantum numbers may be defined as a set of four numbers with the help of which we can get complete information about electron in an atom.

CBSE Class 11 Chemistry Chapter-2 Important Questions


1 Marks Questions

1.Name the sub – atomic particles of an atom.

Ans: Electron, proton and neutron.


2.Name the scientist who first formulated the atomic structure.

Ans: John Dalton, a British teacher in 1808 first proposed a firm scientific basis known as Dalton’s

atomic theory.


3.What is the e/m ratio of an electron?

Ans: According to Thomson’s experiment, e/m ratio for an electron is 


4.What is the charge (e) of an electron?

Ans: From Millikan’s experiment, the charge of an electron (e) is 


5.(i) What is the mass of a proton?                                                                                                  

(ii) What is the charge of a proton?

Ans:(i) The mass of a proton is

(ii) The charge of a proton is 


6.(i) What is the mass of a neutron?                                                                                                               

(ii) What is the charge of a neutron?              

Ans: (i) The mass of a neutron is 

(ii) Neutron is electrically neutral i.e. it has no charge as an electron or a proton has.


7.Name the scientist who first gave the atomic model.

Ans: J.J. Thomson, in 1898 first proposed the atomic model called raising-pudding model.


8.What is an isotope?

Ans:  Atoms of the same elements having same atomic number but different mass number are called isotopes.


9.What are isobars?  

Ans: Atoms of different elements which have same mass number but different atomic nos.

eg:


10.What are isotones?

Ans: Atoms of different elements which contains the same number of neutron.

eg.


11.What is an atomic number?                           

Ans: Atoms of different elements which contains the same number of neutron.

eg.


12.What is a mass number?  

Ans: Maas number of an element is the sum of number of proton and neutron present in the nucleus of an atom.


13.Give the drawbacks of J.J. Thomson’s experiment.         

Ans:  (i) It could not explain the origin of the spectral lines of hydrogen and other atoms,

(ii) It failed to explain scattering of  in Rutherford’s scattering experiment.


14.Why Rutherford’s model could not explain the stability of an atom? 

Ans:According to the electromagnetic theory of Maxwell, charged particles when accelerated should emit electromagnetic radiation. Therefore, an electron in an orbit will emit radiation; the orbit will then continue to shrink which does not happen in an atom.


15.Define photoelectric effect.           

Ans: It is the phenomenon in which the surface of alkali metals like potassium and calcium emit electrons when a beam of light with high frequency is made to fall on them.


16.How does the intensity of light effect photoelectrons?

Ans:   The number of electron ejected and kinetic energy associated with them depend on the brightness of light.


17.What is threshold frequency?

Ans:  The minimum frequency below which photo electric effect is not observed is called threshold frequency (vo)


18.Name the scientist who demonstrated photoelectric effect experiment.                          

Ans: In 1887, H. Hertz demonstrated photo electric effect.


19.What did Einstein explain about photoelectric effect?

Ans: Einstein in 1905 was able to explain the photoelectric effect using Planck’s quantum theory of electromagnetic radiation.


20.Calculate energy of 2mole of photons of radiation whose frequency is 

Ans: Energy (E) of one photon = E = hv

Where 

Energy of 2 mole of photon 


21.States Heisenberg’s Uncertainty Principle.

Ans: It states that  It is impossible to determine simultaneously the exact position and exact momentum (or velocity) of an electron.


22..How would the velocity be effected if the position is known?

Ans: If the position of the electron is known with high degree of accuracy (is small), then the velocity of the electron will be uncertain 


23.We don’t see a car moving as a wave on the road why?

Ans: According to de Broglie’s relation,  the mass of the car is very large and its wavelength  or wave character is negligible. Therefore, we do not see a car moving like a wave.


24.Give the de – Broglie’s relation.

Ans: According to de Broglie, every particle in motion is associated with a wavelength and other wave characteristics. He deduced the relation that wavelength  of a particle in motion is equal to the Planck’s constant (h) divided by the momentum (p) of the particle.

i.e. 

Where m is the mass, is the velocity after particles


25.Calculate the uncertainty in the velocity of a wagon of mass 4000kg whose  position is known accurately of 

Ans:  Uncertainty in velocity  is given by

The uncertainty in the velocity of the wagon is 


26.What is the physical significance of up?              

Ans:  represent probability of finding an electron.


27.Which orbital is non – directional?

Ans:S – orbital is spherically symmetrical i. e it is non – directional.


28.What is the meaning of quantization of energy?

Ans:Quantization of energy means the energy of energy levels can have some specific values and not all the values.


29.Why is energy of 1s electron lower than 2s electron? 

Ans.1s electron being close to the nucleus experiences more force of attraction than 2s– electron which is away from the nucleus.


30.What is nodal surface or nodes? 

Ans:The region where the probability of finding an electron is zero i. e. Y2    = 0


31.How many spherical nodal surfaces are there in 4s – sub-shell? 

Ans:In ns orbital, the number of spherical nodal surfaces are(n – 1), hence is 4s (4 – 1) = 3 nodal surfaces are present.



2 Marks Questions

1.What is the mass (m) of an electron?

Ans: mass of an electron (m) = 

So, the mass of an electron is  or  th of the mass of a hydrogen atom.


2.Which experiment led to the discovery of electrons and how?  

Ans:The cathode ray discharge tube experiment performed by J.J. Thomson led to the discovery of negatively charged particles called electron.

A cathode ray tube consists of two thin pieces of metals called electrodes sealed inside a glass tube with sealed ends. The glass tube is attached to a vacuum pump and the pressure inside the tube is reduced to 0.01mm. When fairly high voltage (10, 000V) is applied across the electrodes, invisible rays are emitted from the cathode called cathode rays. Analysis of this rays led to the discovery electrons.

  


3.Give the main properties of canal ray experiment.

Ans:The canal ray experiment led to the discovery of –

(i)The anode rays, travel in straight line

(ii)They are positively charged as they get deflected towards the –ve end when subjected to an electric and magnetic field.

(iii)They depend upon the nature of gas present in the cathode tube.

(iv)The charge to mass ration (e/m) of the particle is found to depend on the gas from which they originate.

(v)They are also material particles

The analysis of these proportions led to the discovery of positively charged proton.


4.Find out atomic number, mass number, number of electron and neutron in an element?

Ans: The mass no. of 

The atomic no. of  

No. of proton is = Z – A = 40 – 20 = 20

No. of electron its (A) = 20

No. of proton is (A) = 20


5.Give the main features of Thomson’s Model for an atom.

Ans: J.J. Thomson proposed that an atom consists of a spherical sphere (radius of about 10-10m)in which the positive charges are uniformly distributed the electrons are embedded into it in such a manner so as to give stable electrostatic arrangement.

This model is also called raisin pudding model.

 


6.What did Rutherford conclude from the observations of   scattering experiment?

Ans: Rutherford proposed the nuclear model of an atom as

(i) The positive charge and most of the mass of an atom was concentrated in an extremely small region. He called it nucleus.

(ii) The nucleus is surrounded by electrons that move around the nucleus with a very high speed in orbits.

(iii) Electron and nucleus are held together by electrostatic forces of attraction.


7.What is the relation between kinetic energy and frequency of the  photoelectrons?

Ans: Kinetic energy of the ejected electron is proportional to the frequency of the electromagnetic radiation.


8.What transition in the hydrogen spectrum would have the same  wavelength as the Balmer transition, n = 4 to n = 2 of He+ spectrum?

Ans: For the Balmer transition, n = 4, to n = 2 in a He+ ion, we can write.

For a hydrogen atom

Equating equation (ii) and (i), we get

This equation gives n1 = 1 and n = 2. Thus the transition n = 2 to n = 1 in hydrogen atom will have same wavelength as transition, n = 4 to n = 2 in He+


9.Spectral lines are regarded as the finger prints of the elements. Why?

Ans: Spectral lines are regarded as the finger prints of the elements because the elements can be identified from these lines. Just like finger prints, the spectral lines of no two elements resemble each other.


10.Why cannot the motion of an electron around the nucleus be determined

accurately?

Ans: Because there is an uncertainty in the velocity of moving electron around the nucleus (Heisenberg’s Uncertainty Principle).


11.Calculate the uncertainty in the momentum of an electron if it is confined to a linear region of length

Ans: According to uncertainty Principle


12.Give the mathematical expression of uncertainty principle.    

Ans:Mathematically, it can be given as

Where is the uncertainty in position and  is the uncertainty in momentum (or velocity) of the particle.


13.Which quantum number determines

(i)  energy of electron      

(ii) Orientation of orbitals.

Ans. (i) Principal quantum number (n), and

(ii) Magnetic quantum number (m).


14.Arrange the electrons represented by the following sets of quantem number in decreasing order of energy. 

1.   n = 4,  l = 0, m = 0, s = +1/2

2.   n = 3,  l = 1, m = 1,  s = -1/2

3.   n = 3,  l = 2, m = 0, s = +1/2

Ans.(i)Represents 4s orbital

(ii) Represents 3p orbital

(iii)Represents 3d orbital

(iv)Represents 3s orbital

The decreasing order of energy   3d > 4s > 3p > 3s

n = 3,  l = 0, m = 0, s = -1/2



3 Marks Questions

1.What designations are given to the orbitals having

(i)    n = 2, l = 1     (ii)   n = 2, l = 0     (iii) n = 4, l = 3

(iv)   n = 4, l = 2      (v)    n = 4, l = 1? 

Ans.    (i)           Here, n = 2, and l = 1

Since l = 1 it means a p-orbital, hence the given orbital is designated as 2p.

(ii) Here, n = 2 and l = 0

Since l = 0 means s – orbital, hence the given orbital is 2s.

(iii) Here, n = 4 and  l = 3

Since, l = 3 represents f – orbital, hence the given orbital is a 4f orbital.

(iv) Here, n = 4 and l = 2

Since, l = 2 represents d – orbital, hence the given orbital is a 4d – orbital.

(v) n = 4  and l = 1

since, l = 1 means it is a p – orbital, hence the given orbital can be designated as – 4p orbital.


2.Write the electronic configuration of (i) Mn4+, (ii) Fe3+ (iii)  Cr2+ and Zn2+ Mention the number of unpaired electrons in each case.

Ans.(i)       Mn  (z = 25), Mn4+  (z = 21)

The electronic configuration of Mn4+ to Given by

1s2 2s2 2p6 3s2 3p6 3d3

As the outermost shell 3d has 3 electrons, thus the number of unpaired

electrons is 3.

 (ii) Fe   (z = 26), Fe3+ (z = 23)

The electronic configuration of Fe3+ is given lay

1s2 2s2 2p6 3s2 3p6 3d5

The number of unpaired electron is 5.

(iii) Cr (z = 24),  Cr2+ (z = 22)

The electronic configuration of Cr2+ is

1s2 2s2 2p6 3s2 3p6 3d4

The number of unpaired electron is 4.

(iv) Zn (z = 30), Zn2+  (z = 28)

The electronic configuration of Zn2+ is

1s2 2s2 2p6 3s2 3p6 3d10

The number of unpaired electron is 0.

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