AP Chemistry Unit 6.5 Energy of Phase Changes

Energy of Phase Changes  

  • → endothermic (atractive forces are being broken); ← exothermic (attractive forces are forming)
    • Heat of fusion () will be positive for melting and negative for freezing; heat of vaporization will be positive for vaporization and negative for freezing
  • Can’t use q = mcΔT during phase changes bcuz temp remains constant
    • No change in KE, only change in PE

    • During HoV, all the intermolecular forces/attraction are breaking but during HoF are only breaking/separating some
  • Energy required for phase changes (ex: required to melt a substance)
    1. Heat to melting point: q = mcΔT
    2. Melting: q = (moles)()
    3. Add up values

  • Value of c will be different in each phase

   

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