AS & A Level Chemistry 3.4 Covalent bonding and coordinate (dative covalent) bonding : Exam Style Questions Paper 1

Question:

Which species can accept a lone pair of electrons to form a coordinate (dative covalent) bond?

1    \(BF_{3}\)
2    \(H^{+}\)
3    \(CH_{3}^{~+}\)

▶️Answer/Explanation

Ans:C

Question

 Which statement about aluminium chloride is correct?
A   Aluminium chloride has a much higher melting point than magnesium chloride due to the small size of the aluminium ion.
B   Anhydrous aluminium chloride reacts vigorously with water to form a solution with a pH greater than 7.
C   Each \(Al_2Cl_6\) molecule found in aluminium chloride vapour contains two coordinate bonds.
D   The bonding between aluminium and chlorine is strongly ionic due to the large difference in electronegativity.

Answer/Explanation

Ans: C

Question

Which elements form a chloride in which both covalent bonding and coordinate (dative covalent) bonding are present?

1    Al
2   Si
3   Mg

Answer/Explanation

Answer       D

Question

The eight species that follow all have covalent bonds.

In which pair do the species have different shapes from each other?

  BeCl2 and CO2
B    CH4 and NH4+
C    NH3 and BF3
  SCl2 and H2O

Answer/Explanation

Answer:

C

Question

Which types of bonding are present in ammonium carbonate, (NH4)2CO3?
1    ionic
2    covalent
3    co-ordinate (dative covalent)

The responses A to D should be selected on the basis of

Answer/Explanation

Answer:

A

 Question

Which statement is correct?

A Ammonia reacts with alkalis to form the ammonium ion.
B Ammonium chloride contains ionic, covalent and co-ordinate bonds.
C The ammonium ion reacts with acids to produce ammonia.
D The bond angle in the ammonium ion is approximately 107°.

Answer/Explanation

Answer      B

Question

Which row describes the structure and bonding of SiO2 and SiCl4?

Answer/Explanation

Answer        B

Question

The definitions of many chemical terms can be illustrated by chemical equations.
Which terms can be illustrated by an equation that includes the formation of a positive ion?
1 first ionisation energy
2 heterolytic fission of a covalent bond
3 enthalpy change of atomisation

The responses A to D should be selected on the basis of

Answer/Explanation

Ans: B

Question

Which molecule contains a nitrogen atom with sp hybridised orbitals?
A    CH3CH2NH2               B    HNO3               C    HCN               D    NH3

Answer/Explanation

Answer:

C

Question

In the sodium chloride lattice the number of chloride ions that surround each sodium ion is called the co-ordination number of the sodium ions.
What are the co-ordination numbers of the sodium ions and the chloride ions in the sodium chloride lattice?

Answer/Explanation

Ans: C

Question

What is the correct number of bonds of each type in the Al2Cl6 molecule?

Answer/Explanation

Answer:       B

Question

Some car paints contain small flakes of silica, \(SiO_{2}\).
In the structure of solid \(SiO_{2}\)
● each silicon atom is bonded to x oxygen atoms,
● each oxygen atom is bonded to y silicon atoms,
● each bond is a z type bond.
What is the correct combination of x, y and z in these statements?

Answer/Explanation

Ans:C

Question

The table shows the physical properties of four substances. Which substance has a giant covalent structure?

Answer/Explanation

Ans:D

Question

 Which types of bonding are present in ammonium carbonate, \((NH_4)2CO_3\)?

1 ionic
2 covalent
3 co-ordinate (dative covalent)

Answer/Explanation

Ans: A

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