AS & A Level Chemistry 4.2 Bonding and structure Exam Style Practice Questions Paper 1- New Syllabus
Question
Which row describes silicon dioxide?
| Electrical conductivity in liquid state | Solubility in water | |
|---|---|---|
| A | non-conductor | insoluble |
| B | non-conductor | soluble |
| C | conductor | insoluble |
| D | conductor | soluble |
▶️ Answer/Explanation
Correct Answer: \( \boxed{\mathrm{A}} \)
Silicon dioxide has a giant covalent structure.
- It has no mobile ions or delocalised electrons, so it does not conduct electricity, even when molten.
- Its strong three-dimensional covalent network makes it insoluble in water.
Therefore, the correct answer is (A).
Question
In which substance are covalent bonds broken as it melts?
(B) Ice
(C) Iodine
(D) Ethanol
▶️ Answer/Explanation
Correct Answer: \( \boxed{\mathrm{A}} \)
Silicon(IV) oxide has a giant covalent structure. Melting requires breaking some of the strong covalent bonds in the three-dimensional network.
Ice, iodine and ethanol are simple molecular substances. When they melt, only the intermolecular forces (hydrogen bonding or van der Waals’ forces) are overcome, while the covalent bonds within the molecules remain intact.
Therefore, the correct answer is (A).
Question
Substance W has the physical properties shown.
| m.p. / \(^{\circ}\mathrm{C}\) | b.p. / \(^{\circ}\mathrm{C}\) | Electrical conductivity | ||
|---|---|---|---|---|
| Of solid | Of liquid | In water | ||
| 2072 | 2980 | Poor | Good | Insoluble |
What is substance W?
(B) Iron
(C) Silicon dioxide
(D) Sodium fluoride
▶️ Answer/Explanation
Correct Answer: \( \boxed{\mathrm{A}} \)
The substance has a very high melting point and boiling point, indicating a giant lattice structure.
It conducts electricity when molten but not when solid, showing that mobile ions are present only in the liquid state. It is also insoluble in water.
These properties are characteristic of aluminium oxide, a giant ionic compound with very strong electrostatic attractions.
Iron conducts electricity in both the solid and liquid states, silicon dioxide does not conduct in either state, and sodium fluoride is soluble in water.
Therefore, the correct answer is (A).
