Home / AS & A Level Chemistry 9.2 Periodicity of chemical properties of the elements in Period 3 Exam Style Practice Questions Paper 1

AS & A Level Chemistry 9.2 Periodicity of chemical properties of the elements in Period 3 Exam Style Practice Questions Paper 1- New Syllabus

Question

A student investigated the chloride of a Period 3 element. This is what the student wrote down as the observations.

The compound was a white crystalline solid. It dissolved easily in water to give a solution of pH 12. When placed in a test-tube and heated in a roaring Bunsen flame, the compound melted after several minutes’ heating.

What can be deduced from these observations?

(A) At least one of the recorded observations is not correct.
(B) The compound was magnesium chloride, \(\mathrm{MgCl_2}\).
(C) The compound was phosphorus pentachloride, \(\mathrm{PCl_5}\).
(D) The compound was sodium chloride, \(\mathrm{NaCl}\).
▶️ Answer/Explanation

Correct Answer: \( \boxed{\mathrm{A}} \)

The observations are inconsistent with any Period 3 chloride.

  • \(\mathrm{NaCl}\) and \(\mathrm{MgCl_2}\) dissolve in water but do not produce a strongly alkaline solution of pH 12.
  • \(\mathrm{PCl_5}\) reacts violently with water to form acidic products, not an alkaline solution.
  • A solution of pH 12 cannot be obtained from any Period 3 chloride simply by dissolving it in water.

Therefore, at least one of the recorded observations must be incorrect.

Hence, the correct answer is (A).

Question

Element E is in Period 3. It forms a chloride which reacts with a small amount of water to produce a white precipitate and steamy fumes. This precipitate is soluble in \(\mathrm{NaOH(aq)}\) and in \(\mathrm{HCl(aq)}\).

What is element E?

(A) magnesium
(B) aluminium
(C) silicon
(D) phosphorus
▶️ Answer/Explanation

Correct Answer: \( \boxed{\mathrm{B}} \)

Aluminium chloride hydrolyses in a small amount of water:

\(\mathrm{AlCl_3+3H_2O\rightarrow Al(OH)_3+3HCl}\)

The white precipitate is \(\mathrm{Al(OH)_3}\), while hydrogen chloride produces steamy fumes.

Aluminium hydroxide is amphoteric, so it dissolves in both aqueous sodium hydroxide and hydrochloric acid.

Therefore, the correct answer is (B).

Question

Compound X is an oxide of a Period 3 element.

Compound X is a white solid at \(25^\circ\mathrm{C}\). It reacts with water to form an acidic solution.

What is compound X?

(A) aluminium oxide
(B) silicon dioxide
(C) sulfur dioxide
(D) phosphorus(V) oxide
▶️ Answer/Explanation

Correct Answer: \( \boxed{\mathrm{D}} \)

Phosphorus(V) oxide is a white solid that reacts vigorously with water to form phosphoric acid:

\(\mathrm{P_4O_{10}+6H_2O\rightarrow4H_3PO_4}\)

Aluminium oxide is amphoteric, silicon dioxide does not react with water, and sulfur dioxide is a gas at room temperature.

Therefore, the correct answer is (D).

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