Home / iGCSE Chemistry (0620) Core:11.1 Formulae, functional groups and terminology: Exam Style Questions Paper 1

iGCSE Chemistry (0620) Core:11.1 Formulae, functional groups and terminology: Exam Style Questions Paper 1- New Syllabus

Question

Which statements about the alkanes are correct?
  1. They are generally unreactive except in terms of combustion and substitution by chlorine.
  2. They have the general formula $\text{C}_n\text{H}_{2n+2}$.
  3. They contain double carbon-carbon covalent bonds.
  4. They decolourise aqueous bromine.
A. 1, 2 and 3
B. 1 and 2 only
C. 1, 3 and 4
D. 2 and 4
▶️ Answer/Explanation
Correct Option: B

Detailed solution:

Alkanes are saturated hydrocarbons with only single bonds, so statement 3 is false. Because they have no double bonds, they do not decolourise bromine water (statement 4 false). They have the general formula $\text{C}_n\text{H}_{2n+2}$ (statement 2 true) and are generally unreactive except for combustion and substitution reactions (statement 1 true). So, 1 and 2 are correct.

Question

The molecular formulae of four organic compounds, W, X, Y and Z, are shown.
Which statement about compounds W, X, Y and Z is correct?
A. W and Z could both be alcohols.
B. Y is the only compound that could be a carboxylic acid.
C. W is a hydrocarbon.
D. X is ethene.
▶️ Answer/Explanation
Correct Option: B

Detailed solution:

The general formula for a carboxylic acid is $\text{C}_n\text{H}_{2n+1}\text{COOH}$, which works out to $\text{C}_n\text{H}_{2n}\text{O}_2$. Y has the formula $\text{C}_4\text{H}_8\text{O}_2$, which fits this pattern (with $n=4$). W has oxygen but doesn’t fit the alcohol general formula $\text{C}_n\text{H}_{2n+1}\text{OH}$; it’s not an alcohol. W contains oxygen, so it’s not a hydrocarbon. X could be propene, not ethene (ethene is $\text{C}_2\text{H}_4$). So only Y can be a carboxylic acid.

Question

The formulae for three organic compounds are listed.
\[1\quad \mathrm{C}_2\mathrm{H}_4\] \[2\quad \mathrm{C}_4\mathrm{H}_8\] \[3\quad \mathrm{C}_4\mathrm{H}_{10}\]
Which compounds belong to the same homologous series?
A. 1, 2 and 3
B. 1 and 2 only
C. 1 and 3 only
D. 2 and 3 only
▶️ Answer/Explanation
Correct Option: B

Detailed solution:

Members of the same homologous series share the same general formula. Compounds 1 and 2 have formulas $C_2H_4$ and $C_4H_8$, which both fit the general formula for alkenes, $C_nH_{2n}$. They both contain a carbon-carbon double bond and belong to the alkene series. Compound 3 is $C_4H_{10}$, which fits the alkane general formula $C_nH_{2n+2}$ and has only single bonds. Since it belongs to a different homologous series from the other two, only 1 and 2 are in the same series.

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