Home / iGCSE Chemistry 0620 Extended – 6.3 Reversible reactions and equilibrium- Exam Style Questions Paper 2

iGCSE Chemistry 0620 Extended - 6.3 Reversible reactions and equilibrium- Exam Style Questions Paper 2- New Syllabus

Question

Ethanol is manufactured by the addition of steam to ethene.

\(\mathrm{C_2H_4(g) + H_2O(g) \rightleftharpoons C_2H_5OH(g)}\)

The reaction conditions are \(300^{\circ}\mathrm{C}\) and 60 atm.

The forward reaction is exothermic.

Which rows describe the effect on the equilibrium yield of \(\mathrm{C_2H_5OH}\) when the stated change is made?

A. 1 and 2
B. 1 and 3
C. 2 only
D. 3 only

▶️ Answer/Explanation
Statement 1: A catalyst increases the rate of both forward and reverse reactions equally. It does not affect the position of equilibrium or the yield — correct.
Statement 2: The forward reaction is exothermic. Decreasing temperature favours the exothermic reaction, shifting equilibrium to the right, increasing yield — correct.
Statement 3: 2 moles of gaseous reactants → 1 mole of gaseous product. Decreasing pressure favours the side with more gas moles (reactants), shifting equilibrium left, decreasing yield — incorrect.
Answer: (A)

Question

Ethanol is manufactured by the addition of steam to ethene.

\(\mathrm{C_2H_4(g) + H_2O(g) \rightleftharpoons C_2H_5OH(g)}\)

The reaction conditions are \(300^{\circ}\mathrm{C}\) and 60 atm.

The forward reaction is exothermic.

Which rows describe the effect on the equilibrium yield of \(\mathrm{C_2H_5OH}\) when the stated change is made?

A. 1 and 2
B. 1 and 3
C. 2 only
D. 3 only

▶️ Answer/Explanation
Statement 1: A catalyst increases the rate of both forward and reverse reactions equally. It does not affect the position of equilibrium or the yield — correct.
Statement 2: The forward reaction is exothermic. Decreasing temperature favours the exothermic reaction, shifting equilibrium to the right, increasing yield — correct.
Statement 3: 2 moles of gaseous reactants → 1 mole of gaseous product. Decreasing pressure favours the side with more gas moles (reactants), shifting equilibrium left, decreasing yield — incorrect.
Answer: (A)

Question

Which row identifies the conditions used to make sulfur trioxide in the Contact process?

▶️ Answer/Explanation
The Contact process for the conversion of sulfur dioxide to sulfur trioxide: \(2\mathrm{SO_2(g) + O_2(g) \rightleftharpoons 2SO_3(g)}\) uses typical conditions of \(450^{\circ}\mathrm{C}\), \(200\,\mathrm{kPa}\) (\(2\,\mathrm{atm}\)) pressure, and a vanadium(V) oxide (\(\mathrm{V_2O_5}\)) catalyst. Iron is the catalyst used in the Haber process, not the Contact process.
Answer: (B)
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