Home / iGCSE Chemistry 0620 Extended – 9.6 Extraction of metals- Exam Style Questions Paper 2

iGCSE Chemistry 0620 Extended - 9.6 Extraction of metals- Exam Style Questions Paper 2- New Syllabus

Question

Three different reactions that occur during the extraction of aluminium from purified bauxite are listed.

  1. \(\mathrm{Al^{3+} + 3e^- \rightarrow Al}\)
  2. \(\mathrm{C + O_2 \rightarrow CO_2}\)
  3. \(\mathrm{2O^{2-} \rightarrow O_2 + 4e^-}\)

Which reactions occur at the anode?

A. 1 and 2
B. 1 only
C. 2 and 3
D. 3 only

▶️ Answer/Explanation
In the extraction of aluminium by electrolysis:
At the anode (+), oxidation occurs. Reaction 3 (\(\mathrm{2O^{2-} \rightarrow O_2 + 4e^-}\)) is the oxidation of oxide ions at the anode. Reaction 2 (\(\mathrm{C + O_2 \rightarrow CO_2}\)) also occurs at the anode as the oxygen produced reacts with the carbon anodes, causing them to be regularly replaced.
Reaction 1 is reduction and occurs at the cathode (−).
Answer: (C)

Question

Iron is extracted from iron(III) oxide in the blast furnace.

Three steps in the process are listed.

  1. Carbon (coke) is completely oxidised.
  2. Iron(III) oxide is reduced.
  3. Carbon dioxide is reduced to carbon monoxide.

What is the correct order of the steps in the extraction of iron?

A. 1 → 2 → 3
B. 1 → 3 → 2
C. 2 → 1 → 3
D. 3 → 1 → 2

▶️ Answer/Explanation
Step 1: Coke (carbon) is completely oxidised at the bottom of the furnace: \(\mathrm{C + O_2 \rightarrow CO_2}\) (provides heat).
Step 3: Carbon dioxide is reduced to carbon monoxide: \(\mathrm{CO_2 + C \rightarrow 2CO}\).
Step 2: Iron(III) oxide is reduced by carbon monoxide: \(\mathrm{Fe_2O_3 + 3CO \rightarrow 2Fe + 3CO_2}\).
Correct order: 1 → 3 → 2.
Answer: (B)

Question

Iron is extracted from hematite in the blast furnace.

Which reaction increases the temperature in the blast furnace to over \(1500^{\circ}\mathrm{C}\)?

A. calcium carbonate → calcium oxide + carbon dioxide
B. calcium oxide + silicon(IV) oxide → calcium silicate
C. carbon + oxygen → carbon dioxide
D. carbon dioxide + carbon → carbon monoxide

▶️ Answer/Explanation
The highly exothermic reaction between carbon (coke) and oxygen (hot air blast) produces carbon dioxide and releases a large amount of heat energy, which raises the temperature in the blast furnace.
Answer: (C)
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