iGCSE Chemistry 0620 Extended - 8.1 Arrangement of elements- Exam Style Questions Paper 4- New Syllabus
Question
(i) Give three observations when this reaction takes place.
(ii) Name the two products of this reaction.
(i) State the colour of the flame.
(ii) Write the symbol equation for this reaction.
(i) State the term given to the water molecules present in hydrated crystals.
(ii) When hydrated calcium nitrate is heated gently, the following reaction occurs:
$Ca(NO_{3})_{2}\cdot xH_{2}O \rightarrow Ca(NO_{3})_{2} + xH_{2}O$
A sample of hydrated calcium nitrate is heated gently. $3.28\text{ g}$ of $Ca(NO_{3})_{2}$ forms and the mass of the crystals decreases by $1.44\text{ g}$. $[M_{r}: Ca(NO_{3})_{2}, 164; H_{2}O, 18]$. Determine the value of $x$ in $Ca(NO_{3})_{2}\cdot xH_{2}O$.
Calculate the number of moles of $Ca(NO_{3})_{2}$ that remain, the number of moles of $H_{2}O$ given off, and determine the value of $x$.
Most-appropriate topic codes (Cambridge IGCSE Chemistry 0620):
• Topic $8.1$ — Arrangement of elements (Part $\mathrm{(a)}$)
• Topic $2.7$ — Metallic bonding (Part $\mathrm{(b)}$)
• Topic $9.1$ — Properties of metals (Parts $\mathrm{(c)}$, $\mathrm{(d)}$)
• Topic $3.3$ — The mole and the Avogadro constant (Part $\mathrm{(e)}$)
▶️ Answer/Explanation
(a) Strontium (Sr)
Explanation: The period number corresponds to the number of occupied electron shells. The Group II element in Period $5$ is Strontium.
(b) Name: Metallic bonding.
Description: It is the electrostatic attraction between positive ions (cations) arranged in a giant lattice and a ‘sea’ of delocalised (mobile) electrons.
(c)(i) Observations: 1. Effervescence (bubbles of gas), 2. The solid calcium dissolves/disappears, 3. The universal indicator solution turns blue (or purple).
(c)(ii) Products: Calcium hydroxide and hydrogen.
Explanation: Metals reacting with water form metal hydroxides and hydrogen gas. Calcium hydroxide is an alkali, which turns universal indicator blue/purple.
(d)(i) Orange-red (or brick-red).
(d)(ii) $2Ca + O_{2} \rightarrow 2CaO$
(e)(i) Water of crystallisation.
(e)(ii) $x = 4$
Calculation:
Moles of $Ca(NO_{3})_{2} = \frac{3.28}{164} = 0.0200\text{ mol}$
Moles of $H_{2}O$ given off (the mass decrease) $= \frac{1.44}{18} = 0.0800\text{ mol}$
Ratio of $Ca(NO_{3})_{2}$ to $H_{2}O$ is $0.0200 : 0.0800$, which simplifies to $1 : 4$. Therefore, $x = 4$.
