IB DP Chemistry Reactivity 1.3 Energy from fuels - IB Style Questions For HL Paper 1A -FA 2025

Question 

Which statement is a disadvantage of using biofuels instead of fossil fuels?

(A) Land is used that could be used to grow food.
(B) Combustion releases more energy per mol of fuel.
(C) Emissions of \( \mathrm{CO_2} \) to the atmosphere are lower overall.
(D) Crop waste can be used as a fuel.
▶️ Answer/Explanation

Correct Answer: \( \boxed{\mathrm{A}} \)

A disadvantage of biofuels is that crops used to produce them require agricultural land. This land could otherwise be used to grow food crops.

Biofuels can have lower overall \( \mathrm{CO_2} \) emissions because the plants used to produce them absorb \( \mathrm{CO_2} \) during photosynthesis. Crop waste can also provide a useful fuel source.

Therefore, the correct answer is (A).

Question 

Which products may form when propane undergoes incomplete combustion?

(A) \( \mathrm{CO_2} \) and \( \mathrm{H_2} \) only
(B) \( \mathrm{CO} \), \( \mathrm{C} \) and \( \mathrm{H_2} \)
(C) \( \mathrm{CO_2} \), \( \mathrm{H_2O} \) and \( \mathrm{H_2} \)
(D) \( \mathrm{CO_2} \), \( \mathrm{CO} \) and \( \mathrm{C} \)
▶️ Answer/Explanation

Correct Answer: \( \boxed{\mathrm{D}} \)

Incomplete combustion occurs when there is insufficient oxygen for complete conversion of carbon into \( \mathrm{CO_2} \).

Depending on the amount of oxygen available, carbon-containing products such as \( \mathrm{CO_2} \), \( \mathrm{CO} \) and solid carbon, \( \mathrm{C} \), may form.

For example, limited oxygen can result in the formation of carbon monoxide:

\( \mathrm{2C_3H_8+7O_2\rightarrow6CO+8H_2O} \)

Therefore, the products that may form are \( \mathrm{CO_2} \), \( \mathrm{CO} \) and \( \mathrm{C} \), so the correct answer is (D).

Question 

What is the sum of the coefficients when \(1\,\mathrm{mol}\) of propan-1-ol, \( \mathrm{C_3H_7OH} \), undergoes complete combustion?

\( \mathrm{\_\_C_3H_7OH(l)+\_\_O_2(g)\rightarrow\_\_CO_2(g)+\_\_H_2O(l)} \)

(A) \(11.5\)
(B) \(12\)
(C) \(12.5\)
(D) \(13\)
▶️ Answer/Explanation

Correct Answer: \( \boxed{\mathrm{C}} \)

The balanced equation for the complete combustion of propan-1-ol is:

\( \mathrm{C_3H_7OH+\dfrac{9}{2}O_2\rightarrow3CO_2+4H_2O} \)

The coefficients are \(1\), \( \dfrac{9}{2} \), \(3\) and \(4\).

Sum of coefficients:

\(1+\dfrac{9}{2}+3+4=12.5\)

Therefore, the correct answer is (C).

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