IB DP Chemistry - Structure 3.1 The periodic table: Classification of elements- IB Style Questions For HL Paper 1A -FA 2025

Question 

Which element is a p-block metal?

(A) \( \mathrm{Sn} \)
(B) \( \mathrm{Te} \)
(C) \( \mathrm{Cd} \)
(D) \( \mathrm{At} \)
▶️ Answer/Explanation

Correct Answer: \( \boxed{\mathrm{A}} \)

The p-block contains elements whose differentiating electron enters a p-orbital.

Tin, \( \mathrm{Sn} \), is a metal in Group 14 and belongs to the p-block. Its outer electron configuration is:

\( \mathrm{[Kr]\,4d^{10}5s^25p^2} \)

Tellurium and astatine are p-block elements but are classified as non-metals or metalloids, while cadmium is a d-block metal.

Therefore, the correct answer is (A).

Question 

Which oxide is the most basic?

(A) \( \mathrm{MgO} \)
(B) \( \mathrm{Al_2O_3} \)
(C) \( \mathrm{SiO_2} \)
(D) \( \mathrm{SO_3} \)
▶️ Answer/Explanation

Correct Answer: \( \boxed{\mathrm{A}} \)

Across Period 3, the oxides generally become less basic and more acidic from left to right.

\( \mathrm{MgO} \) is a basic ionic oxide and reacts with acids to form a salt and water:

\( \mathrm{MgO+2HCl\rightarrow MgCl_2+H_2O} \)

\( \mathrm{Al_2O_3} \) is amphoteric, \( \mathrm{SiO_2} \) is acidic, and \( \mathrm{SO_3} \) is strongly acidic.

Therefore, the most basic oxide is \( \mathrm{MgO} \), so the correct answer is (A).

Question

Which molecule could give rise to the ¹H NMR spectrum shown below (single peak near ~2 ppm)?
A. CH₃COOCH₃
B. CH₃COOCH₃
C. CH₃CHO
D. CH₃CH₂CH₃

▶️ Answer/Explanation

Correct answer: B

• The spectrum shows only one singlet → all protons must be chemically equivalent.
CH₃COOCH₃ has two equivalent methyl groups giving a single peak around 2 ppm.
• The other molecules have multiple proton environments → multiple signals, not one.

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