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Question 1

(a) A student monitors his pulse rate at rest and during exercise.
Table 1.1 shows the results.
(i) Calculate the difference between his pulse rate at rest and during exercise.
(ii) Complete the sentences to explain the results in Table 1.1.
During exercise, the pulse rate increases because the heart is pumping blood ……………
The pumping action is caused by contraction of the …………… wall of the heart.
To provide the body with more energy, the process of …………… increases.
This process requires increased blood flow to the cells to deliver more …………… and ……………
(b) Genetic predisposition and sex are both risk factors for coronary heart disease.
(i) Describe two dietary recommendations to follow to reduce the risk of developing coronary heart disease.
(ii) Males are more likely to develop coronary heart disease than females. State the sex chromosomes in males.
(c) Male gametes are produced by meiosis.
Describe two ways in which the cells produced by meiosis are different from the cells produced by mitosis.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic B9.2 — Heart (Parts (a)(i)–(ii))
• Topic B7.1 — Diet (Part (b)(i))
• Topic B16.1 — Chromosomes and genes (Part (b)(ii))
• Topic B16.2 — Cell division (Part (c))

▶️ Answer/Explanation

(a)(i) 58 beats per minute

Difference \( = 122 – 64 \).
\( = 58 \) beats per minute.

(a)(ii)

… pumping blood faster.
… contraction of the muscular wall of the heart.
… process of (aerobic) respiration increases.
… deliver more glucose and oxygen.

(b)(i) Any two of:

Don’t consume too much fat.
Don’t consume too much salt / carbohydrate / calories.
Don’t consume excessive alcohol.
Consume a balanced diet / plenty of fibre.

(b)(ii) XY

Males have one X chromosome and one Y chromosome.
Females have two X chromosomes (XX).

(c) Any two of:

Cells produced by meiosis are genetically different from each other.
Cells produced by meiosis contain half the number of chromosomes (are haploid), unlike mitosis which produces genetically identical diploid cells.

Question 2

Clean air contains nitrogen gas and oxygen gas.
(a) State the percentage of nitrogen gas and oxygen gas in clean air.
(b) In a car engine, nitrogen gas and oxygen gas react together.
Nitrogen monoxide, NO, is made.
(i) Construct the balanced symbol equation for this reaction.
(ii) The rate of this reaction increases as the temperature inside the car engine increases.
Explain why. Use ideas about collisions between particles.
(iii) The rate of this reaction increases as the concentration of the oxygen gas increases.
Explain why. Use ideas about collisions between particles.
(c) A catalytic converter removes nitrogen monoxide from the exhaust emissions of a car.
Nitrogen monoxide reacts with carbon monoxide.
Nitrogen and carbon dioxide are made.
Look at the equation for this reaction. It shows all the atoms and all the bonds.
\( 2N{=}O \;+\; 2C{\equiv}O \;\rightarrow\; N{\equiv}N \;+\; 2O{=}C{=}O \)
(i) Draw a circle around each set of bonds which are broken when the reaction takes place.
(ii) When nitrogen monoxide reacts with carbon monoxide, the reaction is exothermic.
Explain why. Use ideas about bond breaking and bond making.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C10.2 — Air quality and climate (Part (a))
• Topic C6.2 — Rate of reaction (Parts (b)(i)–(iii))
• Topic C5.1 — Exothermic and endothermic reactions (Parts (c)(i)–(ii))

▶️ Answer/Explanation

(a) nitrogen gas = 78%, oxygen gas = 21%

Clean, dry air is approximately 78% nitrogen and 21% oxygen.
The remaining ~1% is made up of argon, carbon dioxide, and other trace gases.

(b)(i) \( N_2 + O_2 \rightarrow 2NO \)

One nitrogen molecule reacts with one oxygen molecule to form two molecules of NO.
Atoms are balanced on both sides of the equation.

(b)(ii)

Particles move faster and have more kinetic energy at higher temperature.
More particles have energy greater than or equal to the activation energy.
This increases the rate of successful collisions.

(b)(iii)

Higher concentration means more particles per unit volume.
There is less space between particles, so collisions are more frequent.
This increases the rate of successful collisions.

(c)(i) Circle the \( N{=}O \) bonds and \( C{\equiv}O \) bonds on the reactant side.

These are the bonds present in the reactants, \( NO \) and \( CO \).
These bonds must be broken before new bonds can form in the products.

(c)(ii)

Bond breaking is endothermic and absorbs energy.
Bond making is exothermic and releases energy.
More energy is released in bond making than is absorbed in bond breaking, so the reaction is overall exothermic.

Question 3

Fig. 3.1 shows a 35 kg child sliding down a long wire called a zipline.
(a) The child moves from point X to point Y.
Point X is 18 m vertically above point Y.
(i) Show that as the child moves from point X to point Y, the change in gravitational potential energy is 6300 J.
The gravitational field strength, g, is 10 N/kg.
(ii) As the child moves from point X to point Y, she gains kinetic energy before being slowed by a braking system.
The speed of the child at point Y is 14 m/s.
Calculate the kinetic energy of the child at point Y.
(b) The zipline uses a thick cable made of steel.
The zipline’s steel cable heats up as the child slides from point X to point Y.
(i) State the name of the force which causes the steel cable to heat up.
(ii) State the name of the process that transfers thermal energy in steel.
(iii) Describe, in terms of particles, how energy is transferred by the process named in (b)(ii).
(c) Fig. 3.2 shows a section of the zipline’s steel cable.
The section of steel cable has a mass of 4.2 kg and a volume of \( 5.0 \times 10^{-4} \, \text{m}^3 \). Calculate the density of the steel cable.
(d) Fig. 3.3 shows an extension-load graph for the steel cable.
(i) On Fig. 3.3, label the limit of proportionality with a P.
(ii) Use Fig. 3.3 to calculate the spring constant of the steel cable in N/m.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic P1.6.1 — Energy (Parts (a)(i)–(ii))
• Topic P1.4 — Density (Part (c))
• Topic P1.5.1 — Effects of forces (Parts (b)(i)–(iii), (d)(i)–(ii))

▶️ Answer/Explanation

(a)(i) GPE = 6300 J

\( GPE = mgh = 35 \times 10 \times 18 \).
\( = 6300 \, \text{J} \).

(a)(ii) KE = 3430 J

\( KE = \frac{1}{2}mv^2 = \frac{1}{2} \times 35 \times 14^2 \).
\( = 3430 \, \text{J} \).

(b)(i) friction

Friction between the cable and the moving pulley/harness converts kinetic energy into heat energy.

(b)(ii) conduction

Steel is a solid metal, so thermal energy transfers through it by conduction.

(b)(iii)

Vibrations/oscillations pass from particle to particle along the metal.
Free electrons gain kinetic energy and transfer it through collisions, carrying energy through the metal quickly.

(c) density = 8400 kg/m³

\( \rho = \dfrac{m}{V} = \dfrac{4.2}{5.0 \times 10^{-4}} \).
\( = 8400 \, \text{kg/m}^3 \).

(d)(i) P at (100, 0.5)

The limit of proportionality is the point where the graph stops being a straight line.
This occurs at approximately 100 kN, 0.5 mm on Fig. 3.3.

(d)(ii) spring constant = 200,000,000 N/m

\( k = \dfrac{F}{x} = \dfrac{100\,000}{0.0005} \) (using values from the linear region, converting kN to N and mm to m).
\( = 2.0 \times 10^{8} \, \text{N/m} \).

Question 4

(a) Fig. 4.1 is a diagram of the carbon cycle.
(i) Identify process E in Fig. 4.1.
(ii) Draw one arrow on Fig. 4.1 to represent the process of feeding.
(iii) State the balanced chemical equation for the process occurring at A in Fig. 4.1.
(iv) Name process D in Fig. 4.1 and describe its effect on the atmosphere.
(b) The element carbon is found in proteins.
(i) Name one disease caused by protein-energy malnutrition.
(ii) Name the smaller molecules that proteins are made from.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic B18.3 — Carbon cycle (Parts (a)(i)–(iv))
• Topic B7.1 — Diet (Part (b)(i))
• Topic B4 — Biological molecules (Part (b)(ii))

▶️ Answer/Explanation

(a)(i) fossilisation

Process E shows carbon from dead organisms being converted into fossil fuels.
This long-term burial and transformation process is called fossilisation.

(a)(ii) Arrow drawn from “carbon in plants” to “carbon in animals”.

Feeding represents animals eating plants (or other animals), transferring carbon compounds from the food source to the consumer.

(a)(iii) \( 6CO_2 + 6H_2O \xrightarrow{\text{light, chlorophyll}} C_6H_{12}O_6 + 6O_2 \)

Process A is photosynthesis, converting atmospheric carbon dioxide into glucose in plants.
Light energy and chlorophyll are required for this reaction.

(a)(iv) Name: combustion (of fossil fuels)

Burning fossil fuels releases stored carbon back into the atmosphere as carbon dioxide.
This increases the concentration of carbon dioxide in the atmosphere.

(b)(i) kwashiorkor / marasmus

Both are diseases resulting from insufficient protein and/or energy intake, common where diets lack adequate nutrition.

(b)(ii) amino acids

Proteins are polymers made up of chains of amino acid monomers joined by peptide bonds.

Question 5

(a) Table 5.1 shows some information about particles found in atoms.
Complete Table 5.1.
(b) Fig. 5.1 shows a sodium atom.
(i) A sodium atom, Na, can form a sodium ion, \( Na^+ \).
Describe how a sodium atom forms a sodium ion.
(ii) Write a balanced ionic half equation to show how a sodium atom forms a sodium ion.
Use \( e^- \) to represent an electron.
(c) Table 5.2 gives some information about three halogens. Complete Table 5.2.
(d) Sodium, Na, reacts with chlorine, \( Cl_2 \), to make sodium chloride, NaCl.
(i) Construct the balanced symbol equation for this reaction.
(ii) Sodium chloride, NaCl, is an ionic compound.
Draw a dot-and-cross diagram to show the bonding in sodium chloride.
Include the charges on the ions.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C2.2 — Atomic structure and the Periodic Table (Part (a))
• Topic C2.4 — Ions and ionic bonds (Parts (b)(i)–(ii), (d)(i)–(ii))
• Topic C8.3 — Group VII properties (Part (c))

▶️ Answer/Explanation

(a)

Electrons have negligible mass compared to protons/neutrons and carry a charge of −1.
Protons and neutrons each have a relative mass of 1; protons are +1, neutrons are neutral.

(b)(i) Sodium atom loses one electron.

Sodium has one electron in its outer shell.
Losing this electron gives it a stable, full outer shell and an overall +1 charge, forming \( Na^+ \).

(b)(ii) \( Na \rightarrow Na^+ + e^- \)

This half-equation shows sodium losing one electron to become a positively charged sodium ion.

(c)

Fluorine’s 9 electrons fill as 2 in the first shell and 7 in the second (2.7).
Bromine’s atomic number of 35 matches its total electron count of 2+8+18+7.

(d)(i) \( 2Na + Cl_2 \rightarrow 2NaCl \)

Two sodium atoms react with one chlorine molecule to form two units of sodium chloride.
The equation is balanced with equal Na and Cl atoms on both sides.

(d)(ii)

Sodium transfers its one outer electron to chlorine.
This forms \( Na^+ \) (no outer electrons shown) and \( Cl^- \) (8 outer electrons, gained one), held together by ionic bonding.

Question 6

Fig. 6.1 shows a baby elephant born in a wildlife sanctuary.
The elephant is undergoing a routine health check.
(a) Explain what is wrong with the statement “the weight of the elephant is 480 kg”.
(b) The top speed for a fully grown elephant is 11 m/s.
Calculate the maximum distance that can be covered by an elephant in 120 seconds.
(c) The wildlife sanctuary uses enclosures to keep the elephants safe.
Fig. 6.2 shows an enclosure surrounded by four lamps.
The lamps are connected in parallel.
A switch controls the a.c. power supply to the lamps.
(i) Complete the circuit diagram to show the lamps connected in parallel.
Include the switch in your diagram.
The a.c. power supply has been drawn for you.
(ii) The current through the a.c. power supply is 16 A.
Draw a circle around the correct current through each lamp.
2A     4A     16A     32A     64A
(iii) The potential difference across each lamp is 240 V.
Calculate the power output of each lamp.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic P1.3 — Mass and weight (Part (a))
• Topic P1.2 — Motion (Part (b))
• Topic P4.3.2 — Series and parallel circuits (Parts (c)(i)–(iii))

▶️ Answer/Explanation

(a) 480 kg is the mass, not the weight; weight should be measured in Newtons.

Mass (kg) measures the amount of matter in an object.
Weight (N) is the force of gravity acting on that mass, so the unit should be Newtons, not kilograms.

(b) distance = 1320 m

\( d = v \times t = 11 \times 120 \).
\( = 1320 \, \text{m} \).

(c)(i) Four lamps drawn in parallel, each on its own branch, with the switch placed in the main circuit (in series with the power supply) so it controls all lamps together.

A parallel arrangement means each lamp has its own separate loop back to the power supply.
Placing the switch in the main line ensures it can turn all lamps on or off together.

(c)(ii) 4 A

In a parallel circuit with four identical lamps, the total current splits equally between them.
\( \dfrac{16}{4} = 4 \, \text{A} \) through each lamp.

(c)(iii) power = 960 W

\( P = IV = 4 \times 240 \).
\( = 960 \, \text{W} \).

Question 7

(a) A student investigates the effect of temperature on the rate of transpiration.
(i) Complete Fig. 7.1 by:
  • labelling the x-axis
  • drawing a line to predict the expected results.
(ii) The investigation is repeated at a greater humidity.
Explain the effect of increasing humidity on the rate of transpiration.
(b) Transpiration is the loss of water vapour from the leaves.
(i) Explain why transpiration causes a column of water to move upwards in the xylem.
(ii) State the term that describes how water molecules are held together.
(c) Name two cells in leaves that are adapted for gas exchange.
(d) The process of translocation is also used in plants.
Draw three lines from the word translocation to the boxes on the right to make three correct sentences.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic B8.3 — Transpiration (Parts (a)(i)–(ii))
• Topic B8.1 — Xylem and phloem (Parts (b)(i)–(ii))
• Topic B6.2 — Leaf structure (Part (c))
• Topic B8.4 — Translocation (Part (d))

▶️ Answer/Explanation

(a)(i) x-axis labelled “temperature”; line increasing (and levelling off at higher temperatures).

As temperature rises, water molecules gain more kinetic energy and evaporate faster, so transpiration rate rises.
The line typically curves and levels off since stomata may partially close, or the rate becomes limited by water supply.

(a)(ii) Any three of:

Transpiration rate decreases.
There is an increase in water vapour in the air/atmosphere.
This decreases the water potential (concentration) gradient between the leaf and the air, so less evaporation/diffusion of water vapour occurs out of the stomata.

(b)(i)

Loss of water vapour from leaves creates a “transpiration pull” (tension) at the top of the xylem.
This creates a water potential gradient/difference, drawing water up through the xylem to replace what is lost.

(b)(ii) cohesion

Water molecules stick together through hydrogen bonding, allowing them to be pulled up as a continuous column.

(c) spongy mesophyll cells; guard cells

Spongy mesophyll cells have air spaces between them, increasing surface area for gas exchange.
Guard cells control the opening and closing of stomata, regulating gas exchange.

(d) Translocation:

occurs in the phloem.
involves the movement of amino acids.
transports substances to regions of storage in a plant.

Question 8

Plants need three essential elements: nitrogen, phosphorus and potassium.
These elements are found in fertilisers.
(a) Describe why it is important that farmers use fertilisers containing nitrogen, phosphorus and potassium.
(b) Potassium sulfate, \( K_2SO_4 \), is a fertiliser that contains potassium.
A student makes some potassium sulfate.
He reacts potassium carbonate, \( K_2CO_3 \), with sulfuric acid.
Look at the equation for this reaction.
\( K_2CO_3 \;+\; H_2SO_4 \;\rightarrow\; K_2SO_4 \;+\; CO_2 \;+\; H_2O \)
The student uses 2.76 g of potassium carbonate.
Calculate the mass of potassium sulfate the student makes. Show your working.
[\( A_r \): C, 12; H, 1; K, 39; O, 16; S, 32]
(c) Another student checks that a sample of fertiliser contains potassium.
She uses a flame test.
Describe how she will know if the fertiliser contains potassium.
(d) Ammonia is used to make some fertilisers.
Ammonia is made from nitrogen and hydrogen.
\( N_2 + 3H_2 \rightleftharpoons 2NH_3 \)
(i) The use of a catalyst reduces the cost of making ammonia. Explain how.
(ii) The reaction between nitrogen and hydrogen is reversible. Explain what is meant by a reversible reaction.
(e) Fig. 8.1 shows the percentage of ammonia made at different temperatures and pressures.
Look at Fig. 8.1.
(i) Describe how the percentage of ammonia made changes as the temperature increases.
(ii) State a temperature and pressure which would make 40% of ammonia.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C10.1 — Water (Part (a))
• Topic C3.3 — The mole and the Avogadro constant (Part (b))
• Topic C12.5 — Identification of ions and gases (Part (c))
• Topic C6.2 — Rate of reaction (Parts (d)(i)–(ii), (e)(i)–(ii))

▶️ Answer/Explanation

(a)

Nitrogen, phosphorus and potassium are essential nutrients that plants deplete from soil as they grow.
Fertilisers replace these nutrients to improve crop quality and increase yield, preventing deficiency symptoms such as discoloured leaves.

(b) mass of \( K_2SO_4 \) = 3.48 g

\( M_r(K_2CO_3) = (2\times39)+12+(3\times16) = 138 \); \( M_r(K_2SO_4) = (2\times39)+32+(4\times16) = 174 \).
Using the 1:1 mole ratio: \( \dfrac{174}{138}\times 2.76 = 3.48 \, \text{g} \).

(c) The flame test gives a lilac/purple flame.

Potassium compounds produce a characteristic lilac flame colour when heated, allowing identification.

(d)(i)

A catalyst increases the rate of reaction without being used up.
This allows ammonia to be made faster, sometimes at a lower temperature, reducing energy costs.

(d)(ii)

A reversible reaction can proceed in both the forward and backward directions.
Under the same conditions, reactants can form products, and products can re-form reactants.

(e)(i) The percentage of ammonia made decreases as temperature increases.

The forward reaction (making ammonia) is exothermic.
Increasing temperature favours the reverse (endothermic) reaction, reducing ammonia yield.

(e)(ii) Any one of: 350°C and 125 atm; 400°C and 210 atm; 450°C and 325 atm.

Reading across from 40% on the y-axis to each curve gives the corresponding pressure for that temperature.

Question 9

A student investigates the motion of pollen grains in water seen through a microscope.
The student observes that the pollen grains constantly move short distances in random directions.
(a) Fig. 9.1 shows the pollen grains suspended in water.
(i) State the name given to the motion of these pollen grains.
(ii) Explain why the pollen grains constantly move short distances in random directions.
(b) The microscope uses a thin converging lens to produce an image.
Fig. 9.2 shows a thin converging lens.
(i) Draw a ray diagram on Fig. 9.2 to show the formation of a real image. Label the image with the word image.
(ii) The image formed is a real image. Describe one difference between a real image and a virtual image.
(c) The visible light that passes through the lens is part of the electromagnetic spectrum.
(i) State the speed of visible light in a vacuum.
(ii) γ-rays and radio waves are also part of the electromagnetic spectrum.
Place ticks (✓) in the boxes in Table 9.1 to show which statements are true for γ-rays and radio waves.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic P2.1.2 — Particle model (Parts (a)(i)–(ii))
• Topic P3.2.3 — Thin converging lens (Parts (b)(i)–(ii))
• Topic P3.3 — Electromagnetic spectrum (Parts (c)(i)–(ii))

▶️ Answer/Explanation

(a)(i) Brownian (motion)

This random, jittery motion of small particles suspended in a fluid is called Brownian motion.

(a)(ii)

The pollen grains are constantly hit/collided with by light, fast-moving water particles (molecules).
These random collisions from all directions cause the pollen grains to move in short, random paths.

(b)(i)

Two rays are drawn from the tip of the object: one parallel to the axis refracting through the far focal point, and one through the centre of the lens undeviated.
Where these rays cross beyond the lens marks the tip of the real, inverted image, which should be labelled “image”.

(b)(ii)

A real image can be projected onto a screen, since light rays actually meet there.
A virtual image cannot be projected onto a screen, as the rays only appear to diverge from it.

(c)(i) \( 3 \times 10^{8} \, \text{m/s} \)

This is the speed of all electromagnetic waves travelling through a vacuum.

(c)(ii)

Question 10

The percentage of the population of males and females in different age groups with chronic obstructive pulmonary disease (COPD) in one country is recorded.
Fig. 10.1 shows a graph of the results.
(a) Use evidence from Fig. 10.1 to suggest two risk factors associated with COPD in this country.
(b) The percentage of the population of males and females in different age groups with COPD in one other country is recorded.
The country has a higher percentage of tobacco smokers across all age groups.
Describe and explain the difference you would expect to see in the results.
(c) Table 10.1 shows some components of tobacco smoke and their effects.
Complete Table 10.1.
(d) Smoking also causes an increased concentration of carbon dioxide in the blood.
State the effect of an increased concentration of carbon dioxide in the blood on the gas exchange system.
(e) State the name of the specialised cells that protect the gas exchange system by removing mucus.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic B11 — Gas exchange in humans (Parts (a)–(e))

▶️ Answer/Explanation

(a) age; sex

The graph shows COPD prevalence rising sharply with increasing age.
It also shows males consistently have a higher percentage than females across most age groups.

(b)

You would expect an increased percentage of COPD across all age groups in the country with more smokers.
This is because smoking is a major cause of COPD, so higher smoking rates lead to greater disease prevalence at every age.

(c)

Nicotine is the addictive chemical in tobacco smoke.
Carbon monoxide binds to haemoglobin, reducing the blood’s oxygen-carrying capacity, while tar contains carcinogens that cause cancer.

(d) Increased rate of breathing.

Higher blood \( CO_2 \) is detected by chemoreceptors, which stimulate an increase in breathing rate to remove the excess \( CO_2 \).

(e) Ciliated epithelial cells.

These cells line the airways and use beating cilia to sweep mucus (and trapped particles/pathogens) up and out of the gas exchange system.

Question 11

Fractional distillation of petroleum makes useful fractions.
Three of these fractions are gasoline, gas oil and refinery gas.
(a) Refinery gas contains butane, \( C_4H_{10} \).
Draw a diagram to show the structure of butane.
(b) Fractional distillation makes too much gas oil and not enough gasoline.
Cracking breaks large hydrocarbon molecules into smaller molecules.
State two conditions needed for cracking.
(c) Cracking involves the breaking of covalent bonds within molecules.
Fig. 11.1 shows the structure of dodecane.
The cracking of dodecane makes a mixture of products. Explain why.
(d) Dodecane has the formula \( C_{12}H_{26} \).
During cracking, dodecane can make octane, \( C_8H_{18} \), and ethene, \( C_2H_4 \).
Ethene is an alkene. Alkenes have the general formula \( C_nH_{2n} \).
Dodecane and octane are alkanes.
State the general formula of the alkanes.
(e) In an experiment, 114 g of octane react with oxygen.
The mass of carbon dioxide gas made is 352 g.
Calculate the volume occupied by 352 g of carbon dioxide gas.
Show your working.
The volume of one mole of any gas is 24 dm³ at room temperature and pressure (r.t.p.).
[\( A_r \): C, 12; O, 16]

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C11.4 — Alkanes (Parts (a), (d))
• Topic C11.3 — Fuels (Parts (b), (c))
• Topic C3.3 — The mole and the Avogadro constant (Part (e))

▶️ Answer/Explanation

(a)

Butane is a straight-chain alkane with 4 carbon atoms, each bonded to the maximum number of hydrogens.
Each carbon forms 4 single covalent bonds, satisfying its tetravalency.

(b) Any two of:

A (named) catalyst is used (e.g. zeolite/aluminium oxide/silicon dioxide).
High temperature and/or high pressure are required to break the covalent bonds.

(c)

Any covalent bond within the dodecane chain can break, at a random point along the molecule.
This random breaking produces different-sized fragments, giving a mixture of products such as octane and ethene.

(d) \( C_nH_{2n+2} \)

Alkanes are saturated hydrocarbons with only single bonds, so they have 2 more hydrogen atoms than twice the number of carbons.

(e) volume = 192 dm³

\( M_r(CO_2) = 12 + (2\times16) = 44 \); moles of \( CO_2 = \dfrac{352}{44} = 8 \).
Volume \( = 8 \times 24 = 192 \, \text{dm}^3 \).

Question 12

(a) Fig. 12.1 shows a transformer.
(i) On Fig. 12.1, label the soft-iron core with an X.
(ii) The transformer has 17 turns on the primary coil and 8 turns on the secondary coil.
Calculate the output voltage when the a.c. power supply has an e.m.f. of 34 000 V.
Assume the transformer has an efficiency of 100%.
(b) Fig. 12.2 shows a current-carrying solenoid.
On Fig. 12.2, draw the magnetic field pattern, including direction, around the solenoid.
(c) The radioactive isotope uranium-238 decays into an isotope of thorium by emitting an α-particle.
(i) Use the correct nuclide notation to complete the decay equation for uranium-238.
(ii) Suggest why an α-particle is deflected when moving through a magnetic field.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic P4.5.6 — The transformer (Parts (a)(i)–(ii), (b))
• Topic P4.5.3 — Magnetic effect of current (Part (b))
• Topic P5.2.2 — The three types of nuclear emission (Parts (c)(i)–(ii))

▶️ Answer/Explanation

(a)(i) The soft-iron core is the central bar linking the two coils; it should be labelled X.

The soft-iron core links the primary and secondary coils magnetically, allowing efficient transfer of the changing magnetic field between them.

(a)(ii) output voltage = 16 000 V

Using \( \dfrac{V_p}{V_s} = \dfrac{N_p}{N_s} \): \( V_s = V_p \times \dfrac{N_s}{N_p} = 34\,000 \times \dfrac{8}{17} \).
\( = 16\,000 \, \text{V} \).

(b)

Field lines run parallel and close together inside the solenoid, pointing from one end to the other (like a bar magnet).
Outside the solenoid, the field lines curve round from the north pole end back to the south pole end.

(c)(i) \( {}^{238}_{92}U \rightarrow {}^{234}_{90}Th + {}^{4}_{2}\alpha \)

Mass number decreases by 4 (238 → 234) and atomic number decreases by 2 (92 → 90), consistent with the emission of an alpha particle \( ({}^{4}_{2}\alpha) \).

(c)(ii)

An alpha particle carries a positive charge.
A moving charged particle experiences a force when passing through a magnetic field, causing it to be deflected.

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