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Question 1

(a) Fig. 1.1 is a diagram of the female reproductive system.
Identify the letter from Fig. 1.1 that represents:
where female gametes are released   ……………………………………
where fertilisation occurs                    ……………………………………
where implantation occurs                  ……………………………………
where meiosis occurs.                           ……………………………………
(b) Female gametes in humans are called egg cells.
State the name of the male gamete in humans.
(c) Table 1.1 compares some features of male and female gametes.
Complete Table 1.1.
(d) Complete the sentences to describe the adaptive features of egg cells.
One of the adaptive features of egg cells is that it has ……………………………………….. stores.
The egg cell also has a ……………………………………….. coating that changes after fertilisation.

Most-appropriate topic code (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic B15.4 — Sexual reproduction in humans (Parts (a)–(d))

▶️ Answer/Explanation

(a) female gametes released: E; fertilisation: A; implantation: D; meiosis: E

The ovary (E) is where egg cells are produced and released, and where meiosis occurs during their formation.
The oviduct/fallopian tube (A) is the usual site of fertilisation.
The uterus (D) is where the fertilised egg implants into the lining.

(b) sperm

The male gamete in humans is called the sperm (spermatozoon).
It is produced in the testes and is adapted for motility to reach the egg cell.

(c)

Sperm are small and produced in millions so that a few reach and fertilise the much larger, single egg cell.
Sperm are motile (swim using a flagellum) while the egg cell is non-motile, relying on cilia in the oviduct for movement.

(d) energy; jelly

The egg cell contains energy stores (cytoplasm/yolk reserves) to nourish the early embryo before implantation.
It also has a jelly coating (zona pellucida) that hardens/changes after fertilisation to prevent entry of further sperm (polyspermy).

Question 2

Petroleum is a fossil fuel.
It can be separated into useful fractions by fractional distillation.
Fig. 2.1 shows a diagram of a fractionating column.
(a)(i) Explain why it is possible to separate the substances in petroleum by fractional distillation.
(ii) On Fig. 2.1, write the letter X in the coolest part of the fractionating column.
(b) Table 2.1 shows the uses of some of the fractions.
Complete Table 2.1.
(c) Refinery gas contains propane, \(\text{C}_3\text{H}_8\).
Draw a diagram to show the structure of propane.
(d) Refinery gas also contains butane, \(\text{C}_4\text{H}_{10}\).
Butane burns in oxygen to make carbon dioxide and water.
Construct the balanced symbol equation for this reaction.
(e) Burning butane is a chemical change.
Describe the difference between a chemical change and a physical change.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C11.3 — Fuels (Parts (a), (b))
• Topic C11.1 — Formulas and terminology (Part (c))
• Topic C6.1 — Physical and chemical changes (Parts (d), (e))

▶️ Answer/Explanation

(a)(i) fractions have different boiling points

Each fraction contains hydrocarbons of similar chain length, and different chain lengths have different boiling points.
As vapour rises up the column it cools and each fraction condenses out at the height matching its own boiling point.

(a)(ii) X marked at the top of the column

Temperature decreases going up the fractionating column.
X should be placed at the very top, above the highest fraction outlet, since this is the coolest region.

(b)

(c) straight-chain propane structure

Propane, \(\text{C}_3\text{H}_8\), has three carbon atoms joined by single covalent bonds in a chain.
Each carbon atom is fully saturated, bonded to enough hydrogen atoms to give four bonds in total.

(d) \(2\text{C}_4\text{H}_{10} + 13\text{O}_2 \rightarrow 8\text{CO}_2 + 10\text{H}_2\text{O}\)

Carbon and hydrogen atoms are balanced first, giving 4 \(\text{CO}_2\) and 5 \(\text{H}_2\text{O}\) per butane molecule.
This requires \(6.5\,\text{O}_2\) per butane molecule, so all coefficients are doubled to give whole numbers.

(e) a chemical change forms a new substance

In a chemical change (like burning butane) new substances with different properties are formed, and the change is usually not easily reversed.
In a physical change, no new substance is made — only the state or appearance changes, and it is usually reversible.

Question 3

(a) Fig. 3.1 shows a piece of graphite with an irregular shape.
(i) Describe a method to determine the volume of the piece of graphite.
(ii) The piece of graphite has a mass of 33 g and a volume of 15 cm³. Calculate the density of the piece of graphite.
(b) Graphite can be used as a lubricant in machines with moving parts such as an electric drill.
(i) Describe, in terms of forces and energy transfers, how lubricants increase the efficiency of a machine.
(ii) An electric drill transfers 1200 J of electrical energy to 900 J of useful kinetic energy. Calculate the efficiency of the electric drill.
(iii) The electric motor in the drill has a current of 25 A when using an 18 V battery. Calculate the power output of the motor.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic P1.4 — Density (Part (a))
• Topic P1.5.1 — Effects of forces (Part (b)(i))
• Topic P1.6.4 — Power (Part (b)(ii))
• Topic P4.2.5 — Electrical energy and electrical power (Part (b)(iii))

▶️ Answer/Explanation

(a)(i) displacement method

Submerge the graphite fully in a measuring cylinder partly filled with water.
The volume of water displaced (rise in water level) equals the volume of the graphite.

(a)(ii) 2.2 g/cm³

Density is calculated using \(\rho = \dfrac{m}{V}\).
\(\rho = \dfrac{33}{15} = 2.2 \, \text{g/cm}^3\).

(b)(i) reduces friction, increasing useful energy transfer

Lubricants reduce the friction between moving parts of the machine.
This means less heat energy is wasted, so a greater proportion of the input energy is transferred to useful kinetic energy.

(b)(ii) 75%

Efficiency is calculated using \(\text{efficiency} = \dfrac{\text{useful output energy}}{\text{total input energy}} \times 100\%\).
\(\text{efficiency} = \dfrac{900}{1200} \times 100\% = 75\%\).

(b)(iii) 450 W

Electrical power is calculated using \(P = I \times V\).
\(P = 25 \times 18 = 450 \, \text{W}\).

Question 4

A student investigates the effect of temperature on the rate of photosynthesis.
Fig. 4.1 shows the apparatus they use.
The student counts the number of oxygen bubbles produced in one minute.
He repeats this investigation, changing the temperature of the water each time.
The number of oxygen bubbles produced per minute is equivalent to the rate of photosynthesis.
Table 4.1 shows the results.
(a) State the temperature from Table 4.1 where the rate of photosynthesis is the highest.
(b) Photosynthesis is an enzyme-controlled reaction.
(i) Explain the results in Table 4.1 between 5°C and 15°C.
(ii) State the temperature from Table 4.1 when all the enzymes involved in photosynthesis are completely denatured.
(c) The carbohydrate glucose is also a product of photosynthesis.
Glucose is converted to different substances for transport and storage in a plant.
(i) Describe how carbohydrates are transported in a plant.
(ii) State the larger molecule made from glucose that is used for storage in a plant.
(d) Chlorophyll is also necessary for photosynthesis.
State the energy transfer that chlorophyll is responsible for.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic B6.1 — Photosynthesis (Parts (a), (d))
• Topic B5 — Enzymes (Part (b))
• Topic B8.4 — Translocation (Part (c)(i))
• Topic B4 — Biological molecules (Part (c)(ii))

▶️ Answer/Explanation

(a) 30 °C

The highest bubble count in the table (19 bubbles per minute) occurs at 30 °C.
This indicates the maximum measured rate of photosynthesis in this experiment.

(b)(i) rising temperature increases enzyme activity up to this range

As temperature increases, particles gain more kinetic energy and move faster.
This increases the frequency of successful collisions between enzyme and substrate.
More enzyme-substrate complexes form per second, so the rate of photosynthesis (bubble count) increases.

(b)(ii) 40 °C

At 40 °C, no bubbles are produced, meaning photosynthesis has stopped completely.
This shows all the enzymes controlling photosynthesis have been denatured and can no longer function.

(c)(i) sucrose transported through the phloem by translocation

Glucose is converted to sucrose, a more soluble and stable form for transport.
Sucrose is carried in the phloem tissue from sources (e.g. leaves) to sinks (e.g. roots, fruits) by translocation.

(c)(ii) starch

Glucose molecules are joined together to form starch, an insoluble polysaccharide.
Being insoluble, starch does not affect the water potential of cells, making it ideal for storage.

(d) light energy \(\rightarrow\) chemical energy

Chlorophyll absorbs light energy during photosynthesis.
This light energy is transferred into chemical energy, stored in the bonds of glucose molecules.

Question 5

This question is about electrolysis.
(a) The list shows the particles found in aqueous copper(II) sulfate.
\(\text{Cu}^{2+}\)
\(\text{H}^+\)
\(\text{H}_2\text{O}\)
\(\text{SO}_4^{2-}\)
\(\text{OH}^-\)
State the formula of one particle attracted to the cathode during electrolysis. Choose from the list.
(b) Aqueous copper(II) sulfate conducts electricity.
Explain why.
(c) Fig. 5.1 shows the apparatus used for the electrolysis of aqueous copper(II) sulfate.
(i) State the name given to the positive electrode.
(ii) The purification (refining) of copper uses electrolysis.
Describe how impure copper is purified by electrolysis.
Include ionic half-equations in your answer.
(d) Look at this ionic half-equation.
\(\text{Al}^{3+} + 3\text{e}^- \rightarrow \text{Al}\)
State if this reaction is an example of oxidation or reduction.
Explain your answer.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C4.1 — Electrolysis (Parts (a), (b), (c))
• Topic C6.3 — Redox (Part (d))

▶️ Answer/Explanation

(a) \(\text{Cu}^{2+}\) (or \(\text{H}^+\))

The cathode is the negative electrode, so it attracts positively charged ions.
From the list, \(\text{Cu}^{2+}\) and \(\text{H}^+\) are cations and are attracted to it.

(b) contains ions that are free to move

Aqueous copper(II) sulfate contains free-moving ions such as \(\text{Cu}^{2+}\) and \(\text{SO}_4^{2-}\).
These mobile charged particles act as charge carriers, allowing the solution to conduct electricity.

(c)(i) anode

In electrolysis, the positive electrode is always called the anode.
Oxidation occurs at the anode, and negative ions (anions) are attracted to it.

(c)(ii) impure anode dissolves, pure copper deposits at cathode

Impure copper is used as the anode and a strip of pure copper as the cathode, in copper(II) sulfate solution.
At the anode, copper atoms lose electrons and dissolve into solution: \(\text{Cu} \rightarrow \text{Cu}^{2+} + 2\text{e}^-\).
At the cathode, \(\text{Cu}^{2+}\) ions gain electrons and deposit as pure copper: \(\text{Cu}^{2+} + 2\text{e}^- \rightarrow \text{Cu}\).
Insoluble impurities fall to the bottom as anode sludge.

(d) reduction

The \(\text{Al}^{3+}\) ion is gaining electrons to form \(\text{Al}\) atoms.
Reduction is defined as the gain of electrons, so this half-equation represents reduction.

Question 6

Fig. 6.1 shows a cheetah.
Cheetahs are the fastest land animal and have a top speed of 30 m/s.
(a) State the difference between speed and velocity.
(b) Fig. 6.2 shows a speed–time graph for a cheetah’s journey.
Describe the motion of the cheetah shown in Fig. 6.2.
(c) The mass of the cheetah is 42 kg.
Calculate the kinetic energy of the cheetah when it is running at its maximum speed of 30 m/s.
(d) A cheetah drinks water from a puddle.
Over time, the water in the puddle evaporates.
Evaporation and boiling both turn liquid water into a gas.
(i) State one difference between evaporation and boiling.
(ii) State two ways to increase the rate of evaporation from the puddle.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic P1.2 — Motion (Parts (a), (b))
• Topic P1.6.1 — Energy (Part (c))
• Topic P2.2.2 — Melting, boiling and evaporation (Part (d))

▶️ Answer/Explanation

(a) velocity has a direction, speed does not

Speed is a scalar quantity, measuring only how fast an object moves.
Velocity is a vector quantity, so it also specifies the direction of motion.

(b) accelerates, then moves at constant speed

The cheetah initially accelerates, shown by the steep, rising part of the graph.
The rate of acceleration decreases over time (the curve becomes less steep).
Eventually the cheetah reaches a constant maximum speed, shown by the flat, horizontal part of the graph (zero acceleration).

(c) 18 900 J

Kinetic energy is calculated using \(KE = \dfrac{1}{2}mv^2\).
\(KE = \dfrac{1}{2} \times 42 \times 30^2 = \dfrac{1}{2} \times 42 \times 900 = 18\,900 \, \text{J}\).

(d)(i) evaporation occurs at any temperature, boiling only at the boiling point

Evaporation happens only at the surface of a liquid and can occur at any temperature.
Boiling happens throughout the liquid and only occurs at the liquid’s specific boiling point.

(d)(ii) increase temperature; increase surface area (or increase air movement)

Increasing the temperature of the water gives particles more kinetic energy, so more escape the surface.
Increasing the surface area of the puddle (spreading the water out) exposes more particles to the air, increasing evaporation.
Increasing air movement (draught) over the puddle also removes water vapour faster, maintaining a low concentration of vapour above the surface.

Question 7

(a) The effect of an injection of adrenaline on pulse rate is recorded.
The adrenaline is injected at 1 minute.
Fig. 7.1 shows a graph of the results.
(i) Identify in Fig. 7.1 the pulse rate before the adrenaline injection.
(ii) Describe the immediate effect of the adrenaline injection on pulse rate shown in Fig. 7.1. Use data from the graph to support your answer.
(b)(i) State one effect adrenaline has on the eye.
(ii) Name the nerve that carries impulses from the eye to the brain.
(c) A hormone decreases blood glucose concentration by causing the glucose to be stored.
(i) State the name of the hormone that decreases blood glucose concentration.
(ii) State the name of the organ that produces this hormone.
(iii) State the name of the organ that stores the excess glucose.
(d) Describe two ways the actions of the hormonal system are different from the nervous system.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic B13.2 — Hormones (Part (a))
• Topic B13.1 — Coordination and response (Parts (b), (d))
• Topic B13.3 — Homeostasis (Part (c))

▶️ Answer/Explanation

(a)(i) 65 beats per minute

Before the injection (before 1 minute), the graph shows a steady pulse rate of 65 beats per minute.

(a)(ii) sharp/steep increase

Immediately after the injection, pulse rate rises sharply.
It increases from 65 to about 98 beats per minute, a rise of roughly 33 beats per minute, before gradually falling back down.

(b)(i) pupils dilate (widen)

Adrenaline causes the pupils in the eye to widen (dilate), improving vision in a “fight or flight” response.

(b)(ii) optic nerve

The optic nerve carries electrical impulses from the retina of the eye to the brain for processing.

(c)(i) insulin

Insulin is the hormone that lowers blood glucose concentration.

(c)(ii) pancreas

Insulin is produced and secreted by the pancreas.

(c)(iii) liver

Excess glucose is converted to glycogen and stored mainly in the liver (also in muscles).

(d) hormonal actions are slower and longer-lasting

Hormonal responses act more slowly than nervous responses, since hormones travel in the blood rather than as fast electrical impulses.
Hormonal effects also tend to last longer than the brief, short-lived effects of nervous impulses.

Question 8

Fig. 8.1 shows the arrangement of ions in magnesium metal at 25 °C.
(a) Describe the changes in the arrangement and movement of magnesium ions when magnesium melts.
changes in arrangement of magnesium ions ………………………………………………………………..
changes in movement of magnesium ions ……………………………………………………………………
(b) Magnesium melts at 650 °C and boils at 1090 °C.
In the box, draw the arrangement of ions in magnesium at 1800 °C.
(c) Magnesium reacts with dilute hydrochloric acid. Hydrogen gas is made in the reaction.
A student investigates this reaction. Fig. 8.2 shows the apparatus he uses.
Every 10 seconds, the student measures the total volume of hydrogen gas made.
Fig. 8.3 shows the graph the student plots of his results.
(i) State the volume of gas collected after 40 seconds.
(ii) The reaction is fastest during the first 10 seconds. Explain why.
(iii) The student repeats the experiment.
He uses the same volume of hydrochloric acid and the same mass of magnesium.
This time he increases the temperature of the hydrochloric acid.
All of the magnesium reacts with the acid.
On Fig. 8.3, sketch the shape of the graph you would expect this time.
(d) The rate of the reaction can be increased by increasing the concentration of the dilute hydrochloric acid.
Explain why. Use ideas about collisions between particles.
(e) Magnesium chloride is also made in the reaction between magnesium and dilute hydrochloric acid.
Magnesium chloride contains the ions \(\text{Mg}^{2+}\) and \(\text{Cl}^-\).
Determine the formula of magnesium chloride.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C1.1 — Solids, liquids and gases (Parts (a), (b))
• Topic C6.2 — Rate of reaction (Parts (c), (d))
• Topic C2.4 — Ions and ionic bonds (Part (e))

▶️ Answer/Explanation

(a) arrangement becomes random; ions move around each other

On melting, the regular, ordered arrangement of magnesium ions becomes random/irregular.
The ions change from vibrating about fixed positions to moving freely around each other.

(b) widely spaced, randomly arranged particles

At 1800 °C magnesium is above its boiling point, so it exists as a gas.
The box should show particles drawn far apart and randomly arranged, not touching each other.

(c)(i) 48 cm³

Reading the graph at \(t = 40\,\text{s}\) gives a volume of hydrogen gas of \(48\,\text{cm}^3\).

(c)(ii) acid concentration and magnesium surface area are highest at the start

At the start, the acid is at its most concentrated and the magnesium ribbon has its full surface area exposed.
This gives the highest frequency of collisions between particles, so the reaction proceeds fastest.

(c)(iii) steeper initial slope, same final volume

A higher acid temperature gives particles more kinetic energy, increasing the frequency and energy of collisions.
The new graph should rise more steeply at first, reaching completion sooner, but should still level off at \(58\,\text{cm}^3\) since the same amounts of reactants are used.

(d) more particles per unit volume increases collision frequency

A more concentrated acid has more acid particles in the same volume.
This increases the frequency of collisions between acid and magnesium particles, increasing the number of successful collisions per second and so the rate of reaction.

(e) \(\text{MgCl}_2\)

\(\text{Mg}^{2+}\) has a charge of \(+2\), and \(\text{Cl}^-\) has a charge of \(-1\).
Two \(\text{Cl}^-\) ions are needed to balance the charge of one \(\text{Mg}^{2+}\) ion, giving the formula \(\text{MgCl}_2\).

Question 9

A student investigates the effect of changing light levels on the resistance of a light-dependent resistor (LDR).
The student shines a torch (flashlight) on to the LDR.
She then places glass slides between the LDR and the torch (flashlight) to reduce the light intensity (amount of light) reaching the LDR.
Fig. 9.1 shows the equipment she uses.
The student places more glass slides between the torch (flashlight) and the LDR and measures the resistance, in kilo-ohms (kΩ), using a resistance meter.
(a) Fig. 9.2 shows a graph of the student’s results.
(i) Use Fig. 9.2 to describe how the resistance of the LDR varies with changing light intensity.
(ii) The resistance meter provides a potential difference (p.d.) of 14 V across the LDR.
Calculate the charge flowing through the LDR in 1 minute when 3 glass slides are used.
(b) The lamp emits visible light at a frequency of \(5.0 \times 10^{14}\,\text{Hz}\).
(i) State the meaning of the word frequency.
(ii) Calculate the wavelength of this visible light.
(iii) State one form of electromagnetic radiation that has a frequency higher than visible light.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic P4.2.4 — Resistance (Part (a)(i))
• Topic P4.2.1 — Electrical charge (Part (a)(ii))
• Topic P3.1 — General properties of waves (Part (b)(i), (ii))
• Topic P3.3 — Electromagnetic spectrum (Part (b)(iii))

▶️ Answer/Explanation

(a)(i) resistance increases as light intensity decreases

As more glass slides are added, less light reaches the LDR, so its resistance increases.
The increase is not linear — resistance rises steeply at first, then more gradually as further slides are added.

(a)(ii) 0.0012 C

From the graph, resistance at 3 slides is \(R \approx 700\,\text{k}\Omega = 700\,000\,\Omega\).
Current: \(I = \dfrac{V}{R} = \dfrac{14}{700\,000} = 2 \times 10^{-5}\,\text{A}\).
Charge: \(Q = I \times t = 2\times10^{-5} \times 60 = 0.0012\,\text{C}\).

(b)(i) number of waves passing a point per second

Frequency is the number of complete wave oscillations (cycles) passing a fixed point in one second, measured in hertz (Hz).

(b)(ii) \(6.0 \times 10^{-7}\,\text{m}\)

The wave equation \(c = f\lambda\) is rearranged to \(\lambda = \dfrac{c}{f}\), using \(c = 3\times10^8\,\text{m/s}\).
\(\lambda = \dfrac{3\times10^8}{5.0\times10^{14}} = 6.0\times10^{-7}\,\text{m}\).

(b)(iii) ultraviolet (or X-rays / gamma rays)

Ultraviolet radiation has a higher frequency than visible light in the electromagnetic spectrum.

Question 10

(a) The blood group of some patients in hospital is recorded.
Fig. 10.1 shows a bar chart of the results.
(i) One of the blood groups in Fig. 10.1 is not labelled. State this blood group.
(ii) Identify the most common blood group in Fig. 10.1.
(iii) Describe evidence from Fig. 10.1 that shows that this characteristic is an example of discontinuous variation.
(iv) State the cause of the variation seen in Fig. 10.1.
(b) Adaptations in populations can be inherited through natural selection or selective breeding.
Table 10.1 compares some features of natural selection and selective breeding.
Complete Table 10.1 by placing ticks (✓) in the boxes to show the correct features.
(c) Sexual reproduction is involved in both natural selection and selective breeding.
State two disadvantages of sexual reproduction to a population of species in the wild.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic B9.4 — Blood (Part (a)(i), (ii))
• Topic B17.1 — Variation (Part (a)(iii))
• Topic B16.1 — Chromosomes and genes (Part (a)(iv))
• Topic B17.2 — Selection (Part (b))
• Topic B15.2 — Sexual reproduction (Part (c))

▶️ Answer/Explanation

(a)(i) AB

The bar chart shows blood groups A, B and O labelled; the fourth, unlabelled bar represents blood group AB.

(a)(ii) O

Blood group O has the tallest bar (highest frequency, 16 patients), making it the most common group shown.

(a)(iii) limited, distinct phenotypes with no intermediates

There are only a small number of distinct blood group categories (A, B, AB, O).
There are no intermediate values between these categories, which is characteristic of discontinuous variation.

(a)(iv) genes/alleles

Blood group is determined entirely by the genes/alleles a person inherits from their parents, with no environmental influence.

(b)

Both processes pass alleles to offspring and occur over many generations.
Only selective breeding is deliberately used to improve domesticated animals; only natural selection keeps features best suited to the (natural) environment.

(c) takes time/energy to find a mate; can produce unfavourable gene combinations

Sexual reproduction requires an organism to spend time and energy finding a mate, which is not needed in asexual reproduction.
It can also produce offspring with unfavourable combinations of alleles, which may reduce their chance of survival.

Question 11

Sulfuric acid is made by the Contact process.
Sulfur, air and water are raw materials used to make sulfuric acid.
Look at the equations for the first two stages in the Contact process.
stage 1 ……………………………………… + ……………………………………… \(\rightarrow\) sulfur dioxide
stage 2 sulfur dioxide + oxygen \(\rightleftharpoons\) sulfur trioxide
(a) Complete the word equation for stage 1 of the Contact process.
(b) The conditions used for stage 2 are:
  • 450°C
  • atmospheric pressure
  • a catalyst.
(i) State the name of the catalyst used.
(ii) Explain why a catalyst and a temperature of 450°C are used in stage 2 of the Contact process.
Use ideas about:
  • the percentage of sulfur trioxide made
  • the rate of reaction.
(c) The reaction in stage 2 of the Contact process is exothermic.
Fig. 11.1 shows the energy level diagram for the reaction.
Complete the labels on Fig. 11.1.
Choose the labels from the list.
energy given out
energy taken in
products
reactants
reactants have less energy
(d) In an experiment, 200 g of sulfur trioxide, \(\text{SO}_3\), is made.
Calculate the volume occupied by 200 g of sulfur trioxide gas.
The relative molecular mass, \(M_r\), of sulfur trioxide is 80.
The volume of one mole of any gas is \(24\,\text{dm}^3\) at room temperature and pressure (r.t.p.). Show your working.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C6.2 — Rate of reaction (Parts (a), (b))
• Topic C5.1 — Exothermic and endothermic reactions (Part (c))
• Topic C3.3 — The mole and the Avogadro constant (Part (d))

▶️ Answer/Explanation

(a) sulfur + oxygen

In stage 1, sulfur is burned in oxygen (from the air) to form sulfur dioxide.

(b)(i) vanadium(V) oxide

Vanadium(V) oxide (\(\text{V}_2\text{O}_5\)) is the catalyst used to speed up stage 2 of the Contact process.

(b)(ii) — question removed from paper (no mark scheme content)

For reference, the catalyst increases the rate of reaction without affecting the equilibrium percentage yield, while 450°C is a compromise temperature giving an acceptable rate without lowering the equilibrium yield too much (the forward reaction is exothermic).

(c) reactants (top), energy given out (arrow), products (bottom)

In an exothermic reaction, the reactants start at a higher energy level than the products.
The vertical drop between them, labelled “energy given out,” represents energy released to the surroundings.

(d) 60 dm³

Moles of \(\text{SO}_3\): \(n = \dfrac{200}{80} = 2.5\,\text{mol}\).
Volume at r.t.p.: \(V = 2.5 \times 24 = 60\,\text{dm}^3\).

Question 12

Fig. 12.1 shows a forklift truck lifting a crate.
(a) The forklift truck does 2750 J of work on the crate when the crate is lifted through a height of 2.2 m.
The gravitational field strength, g, is 10 N/kg.
Calculate the mass of the crate.
(b) Fig. 12.2 shows the same forklift truck after it has lowered the crate.
Explain why the forklift truck is more stable after it has lowered the crate.
Use ideas about centre of mass in your answer.
(c) The forklift truck uses an electric motor to lift the crate.
Fig. 12.3 shows a simple d.c. motor.
(i) A current flows through the coil. Draw arrows on Fig. 12.3 to show the direction of the force acting on points X and Z on the coil.
(ii) State why point Y does not experience a force.
(d) A β-particle passes between the poles of a permanent magnet.
(i) Suggest why a β-particle is deflected when moving through a magnetic field.
(ii) State and explain how the deflection direction of an α-particle would differ from that of the β-particle.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic P1.6.2 — Work (Part (a))
• Topic P1.5.3 — Centre of gravity (Part (b))
• Topic P4.5.4 — Force on a current-carrying conductor (Part (c))
• Topic P5.2.2 — The three types of nuclear emission (Part (d))

▶️ Answer/Explanation

(a) 125 kg

Work done against gravity is \(W = mgh\), so \(m = \dfrac{W}{gh}\).
\(m = \dfrac{2750}{10 \times 2.2} = \dfrac{2750}{22} = 125\,\text{kg}\).

(b) lower centre of mass

Lowering the crate lowers the overall centre of mass of the forklift truck system.
A lower centre of mass increases stability, since a larger tilt is needed before the line of action of weight moves outside the base, reducing the tendency to topple.

(c)(i) X: force upwards; Z: force downwards

Using Fleming’s left-hand rule with current and the magnetic field direction shown, the force on X acts upwards and the force on Z acts downwards.
These opposite forces on either side of the coil create the turning effect (torque) that rotates the motor.

(c)(ii) current is parallel to the magnetic field at Y

A force is only produced when current flows at an angle to the magnetic field.
At point Y, the current direction is parallel to the field lines, so no force acts on it.

(d)(i) it is a charged particle

A β-particle is a fast-moving electron and therefore carries a (negative) electric charge.
A charged particle moving through a magnetic field experiences a force (the motor effect), which deflects its path.

(d)(ii) opposite direction, smaller deflection

An α-particle carries a positive charge, opposite to the negative charge of a β-particle, so it deflects in the opposite direction.
Because an α-particle has a much greater mass than a β-particle, it deflects less for the same force.

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