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Question 1

(a) Fig. 1.1 is a diagram of a marine food web.
Table 1.1 shows terms used to describe the organisms in Fig. 1.1.
Place ticks (✓) in the boxes to show the term(s) used to describe each organism.
(b) An orca eats arctic cod and leopard seal.
Add this information to the food web in Fig. 1.1.
(c) State the principal source of energy for all food chains.
(d) The process of photosynthesis occurs in some marine organisms.
(i) State the word equation for photosynthesis.
(ii) State the name of the cell structure where photosynthesis occurs.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic B18.2 — Food chains and food webs (Parts (a), (b))
• Topic B18.1 — Energy flow (Part (c))
• Topic B6.1 — Photosynthesis (Part (d))

▶️ Answer/Explanation

(a)

Arctic cod: primary consumer and secondary consumer (it eats phytoplankton and krill).
Krill: herbivore and primary consumer (it feeds on phytoplankton).
Phytoplankton: producer (it makes its own food by photosynthesis).
Leopard seal: secondary consumer (it eats krill, a primary consumer).
1 mark is awarded for each correctly completed row.

(b) Arrows drawn from arctic cod and leopard seal to orca

A food web arrow always points from the organism being eaten to the organism that eats it.
Since the orca eats both arctic cod and leopard seal, two new arrows must be added.
One arrow goes from arctic cod to orca, and another from leopard seal to orca.

(c) The Sun

Sunlight provides the energy that producers, such as phytoplankton, capture during photosynthesis.
This light energy is converted into chemical energy stored in glucose.
All other organisms in the food chain ultimately depend on this transferred energy.

(d)(i) carbon dioxide + water \(\rightarrow\) glucose + oxygen

Photosynthesis uses light energy to convert carbon dioxide and water into glucose.
Oxygen is released as a by-product of this reaction.
Both reactant names and both product names are required for full marks.

(d)(ii) Chloroplast

The chloroplast contains chlorophyll, the pigment that absorbs light energy.
This light energy drives the reactions of photosynthesis inside the organelle.
Only plant and algal cells (not animal cells) contain chloroplasts.

Question 2

(a) Chlorine, bromine and iodine are halogens in Group VII of the Periodic Table.
Some of these statements about the halogens are correct and some are incorrect.
Place a tick (✓) in the boxes next to the correct statements.
(b) A chlorine atom has a nucleon number of 37 and has 17 electrons.
(i) Determine the number of protons and the number of neutrons in this chlorine atom.
(ii) State the part of the atom that contains the protons and neutrons.
(c) Chlorine is made during the electrolysis of concentrated aqueous sodium chloride as shown below in Fig. 2.1.
(i) State the electrode at which chlorine forms during this process.
(ii) State the other gaseous product of this electrolysis.
(iii) Explain why graphite is used to make the electrodes.
(iv) Explain why electrolysis is an example of a chemical change and not a physical change.
(d) Explain why the drinking water supply for a town is treated with chlorine.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C8.3 — Group VII properties (Part (a))
• Topic C2.2 — Atomic structure and the Periodic Table (Part (b))
• Topic C4.1 — Electrolysis (Part (c))
• Topic C10.1 — Water (Part (d))

▶️ Answer/Explanation

(a)

The correct statements are “the halogens are elements” and “the halogens exist as diatomic molecules”.
Halogens do not form covalent molecules with metals; they form ionic compounds with metals.
Reactivity of the halogens actually decreases down the group, not increases.

(b)(i) Protons = 17, Neutrons = 20

The number of protons equals the number of electrons in a neutral atom, so protons \(= 17\).
The number of neutrons is found from the nucleon number minus the proton number.
Neutrons \(= 37 – 17 = 20\).

(b)(ii) Nucleus

The nucleus is the dense central part of the atom.
It contains all the protons and neutrons of the atom.
Electrons orbit around the nucleus in shells.

(c)(i) Anode (positive electrode)

During electrolysis, negatively charged chloride ions are attracted to the positive electrode.
At the anode, chloride ions lose electrons (are oxidised) to form chlorine gas.
This is why chlorine forms at the anode.

(c)(ii) Hydrogen

At the cathode, positively charged hydrogen ions gain electrons (are reduced).
This produces hydrogen gas at the negative electrode.
Sodium hydroxide solution is also formed, but this is not a gas.

(c)(iii) Graphite is inert / does not react / is a good electrical conductor

Graphite does not react with the products of electrolysis, such as chlorine.
It conducts electricity well, allowing current to pass through the solution.
This makes it a suitable, unreactive electrode material.

(c)(iv) New substances are formed and the change cannot be reversed

In electrolysis, sodium chloride solution is converted into new substances: chlorine, hydrogen and sodium hydroxide.
This shows that a chemical reaction has taken place.
Physical changes do not produce new substances and are usually reversible.

(d) Chlorine kills microbes / sterilises the water

Chlorine is added to drinking water to kill harmful microorganisms and bacteria present in the water.
This prevents the spread of waterborne diseases.
It makes the water safe for human consumption.

Question 3

(a) Fig. 3.1 shows a stationary car.
Part of each tyre is in contact with the road.
State the two quantities needed to calculate the pressure exerted by the car on the road.
(b)
(i) Many car wheels are made from either steel or an aluminium alloy.
Describe a simple test to show that a wheel is not made from steel.
(ii) The car driver loosens the wheel nuts.
He puts a spanner on a wheel nut as shown in Fig. 3.2.
The driver applies a force of \(250\,\text{N}\) at a distance of \(0.4\,\text{m}\) from the wheel nut.
Calculate the moment of the force about the centre of the wheel nut.
(iii) The car driver uses a pump powered by an electric motor to inflate the tyre.
The turning effect of an electric motor can be increased by increasing the number of turns on the coil in the motor.
State one other way to increase the turning effect of a d.c. motor.
(c) Fig. 3.3 shows the car travelling along a road.
As the car moves along the road, electrostatic charges build up on the car. Complete the sentences.
The force that causes the build-up of electrostatic charges on the car is …………………………. .
The charged particles that are added or removed during the build-up of charge are called …………………………. .

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic P1.7 — Pressure (Part (a))
• Topic C9.3 — Alloys and their properties (Part (b)(i))
• Topic P1.5.2 — Turning effect of forces (Part (b)(ii))
• Topic P4.5.5 — The d.c. motor (Part (b)(iii))
• Topic P4.2.1 — Electrical charge (Part (c))

▶️ Answer/Explanation

(a) Weight of the car; surface area of tyres in contact with the road

Pressure is calculated using \(\text{pressure} = \dfrac{\text{force}}{\text{area}}\).
The force here is the weight of the car pressing down on the road.
The area is the total contact area of all the tyres touching the road surface.

(b)(i) Use a magnet — the wheel is not attracted to it

Steel is magnetic, so a magnet will be attracted to a steel wheel.
An aluminium alloy wheel is not magnetic, so a magnet held near it will show no attraction.
This simple test distinguishes between the two materials.

(b)(ii) 100 N m

Moment is calculated using \(\text{moment} = \text{force} \times \text{perpendicular distance}\).
Moment \(= 250\,\text{N} \times 0.4\,\text{m}\).
Moment \(= 100\,\text{N m}\).

(b)(iii) Increase the current, increase the voltage, or increase the strength of the magnetic field

A stronger magnetic force is produced by increasing the current flowing through the coil.
Using a stronger magnet also increases the turning effect (torque) on the coil.
Either of these changes increases the force on the current-carrying coil.

(c) Friction; electrons

Friction between the tyres and the road (or the car and the air) causes electrons to be transferred.
This transfer of electrons results in a build-up of electrostatic charge on the car.
The charged particles involved in this process are electrons.

Question 4

(a) Polydactyly is a condition that results in the growth of extra fingers or toes.
The allele for polydactyly is dominant \(D\).
The allele for no polydactyly is recessive \(d\).
Table 4.1 shows the genotypes of one family.
State the number of people in Table 4.1:
with polydactyly ……………………………………………………….
with a heterozygous genotype ……………………………………………………….
(b) The parents in Table 4.1 have another child.
Complete the genetic diagram in Fig. 4.1 to show the percentage likelihood of the offspring not having polydactyly.
(c) Genes and chromosomes are involved in inheritance.
(i) Define the term gene.
(ii) State the sex chromosomes present in the body cells of human males.
(iii) State the name of the structure in cells that contains the genetic material.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic B16.3 — Monohybrid inheritance (Parts (a), (b))
• Topic B16.1 — Chromosomes and genes (Part (c))

▶️ Answer/Explanation

(a) 5 people with polydactyly; 4 people with a heterozygous genotype

Polydactyly is caused by the dominant allele \(D\), so any genotype containing \(D\) (i.e. \(Dd\) or \(DD\)) shows polydactyly.
From Table 4.1, parent A \((Dd)\), parent B \((Dd)\), offspring Q \((Dd)\), offspring S \((Dd)\) and offspring U \((DD)\) all show polydactyly, giving \(5\) people.
A heterozygous genotype is \(Dd\): parent A, parent B, offspring Q and offspring S, giving \(4\) people.

(b) 25%

Both parent A and parent B have genotype \(Dd\), so each produces gametes \(D\) and \(d\).
The Punnett square gives offspring genotypes \(DD\), \(Dd\), \(Dd\), \(dd\).
Only \(dd\) does not show polydactyly, giving \(\frac{1}{4} \times 100 = 25\%\).

(c)(i) A gene is a length of DNA that codes for a protein

A gene is a section (or length) of the DNA molecule.
Each gene codes for the production of one specific protein.

(c)(ii) XY

Human body cells contain 23 pairs of chromosomes, one pair being the sex chromosomes.
In males, the sex chromosomes are one X chromosome and one Y chromosome \((XY)\).

(c)(iii) Nucleus

The nucleus is the structure within a cell that contains the chromosomes.
Chromosomes are made of DNA, which carries the genetic material of the organism.

Question 5

(a) A student investigates the rate of reaction between calcium carbonate and hydrochloric acid.
The student does the experiment four times and each time uses:
  • the same mass of calcium carbonate
  • different sizes of calcium carbonate pieces
  • a different concentration of hydrochloric acid.
Table 5.1 shows the four experiments, A, B, C and D.
(i) State which experiment has the fastest rate of reaction.
(ii) The student measures the rate of reaction by timing how long it takes for the calcium carbonate pieces to disappear.
Suggest the piece of apparatus the student uses to measure a time of \(100 \, \text{s}\).
(b) The student wants to determine the pH of the acid. She puts some universal indicator paper into the acid.
(i) Describe how the student uses the colour of the universal indicator paper to determine the pH of the hydrochloric acid and its relative acidity.
(ii) Suggest the pH of dilute hydrochloric acid.
(c) Hydrogen chloride, \(\text{HCl}\), dissolves in water to make hydrochloric acid.
(i) Complete the dot-and-cross diagram in Fig. 5.1 to show the bonding in a molecule of hydrogen chloride.
Only show the outer shell electrons.
(ii) State the name of this type of chemical bonding.
(d) Hydrogen chloride is a gas. Water is a liquid.
Describe the difference in the structure between a liquid and a gas, in terms of particle separation and the motion of the particles.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C6.2 — Rate of reaction (Part (a))
• Topic C7.1 — The characteristic properties of acids and bases (Part (b))
• Topic C2.5 — Simple molecules and covalent bonds (Part (c))
• Topic C1.1 — Solids, liquids and gases (Part (d))

▶️ Answer/Explanation

(a)(i) Experiment D

Experiment D uses small pieces of calcium carbonate (greater surface area) with concentrated hydrochloric acid.
Both factors increase the frequency of collisions, giving the fastest rate of reaction.

(a)(ii) Stopwatch

A stopwatch is the appropriate apparatus for accurately timing an interval such as \(100 \, \text{s}\).

(b)(i) Check colour against a pH chart

The colour of the indicator paper is compared to a standard pH colour chart.
A red colour corresponds to pH 1–3 (very acidic), while orange/yellow corresponds to pH 4–6 (weakly acidic).

(b)(ii) Any value between pH 1 and 6

Dilute hydrochloric acid is acidic, so any pH value in the acidic range (below 7) is acceptable.

(c)(i)

Hydrogen contributes one electron and chlorine contributes one electron to form a single shared pair.
The remaining outer shell electrons on chlorine (three lone pairs) are shown unshared.

(c)(ii) Covalent bonding

This type of bonding, involving a shared pair of electrons, is called covalent bonding.

(d) Particle separation and motion

Particle separation: particles in a liquid are close together, whereas particles in a gas are far apart.
Motion: particles in a liquid move around and slide past each other (slower), whereas particles in a gas move randomly and freely at higher speed.

Question 6

(a) Fig. 6.1 shows how the energy transfers in a television when 100 J of electrical energy are supplied.
(i) Calculate the energy transferred as sound.
(ii) Complete the sentences using the energy transfers shown in Fig. 6.1.
The television is designed to transfer …………….. energy to …………….. energy and …………….. energy. …………….. energy is wasted by the television.
(iii) The weight of the television is \(120 \, \text{N}\).
Calculate the mass of the television.
The gravitational field strength, \(g\), is \(10 \, \text{N/kg}\).
(b) Fig. 6.2 shows the power socket which supplies electricity to a television, a laptop and a printer.
(i) State the electrical hazard visible on Fig. 6.2.
(ii) Explain why the hazard identified in (b)(i) is not safe.
(c) A ray of light from the television is reflected by a mirror.
This is shown in Fig. 6.3.
(i) State the name of the line XY.
(ii) State which angle, a, b, c or d, is the angle of incidence.
(iii) State the relationship between the angle of incidence and the angle of reflection.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic P1.6.1 — Energy (Part (a)(i)–(ii))
• Topic P1.3 — Mass and weight (Part (a)(iii))
• Topic P4.4 — Electrical safety (Part (b))
• Topic P3.2.1 — Reflection of light (Part (c))

▶️ Answer/Explanation

(a)(i) 5 J

From Fig. 6.1, total energy supplied \(= 100 \, \text{J}\), with \(65 \, \text{J}\) as light and \(30 \, \text{J}\) as thermal energy.
Energy as sound \(= 100 – 65 – 30 = 5 \, \text{J}\).

(a)(ii) electrical → light and sound; thermal is wasted

The television is designed to transfer electrical energy into light energy and sound energy (its useful output).
Thermal energy is the wasted output, since it does not contribute to the television’s purpose.

(a)(iii) 12 kg

Weight = mass × \(g\), so mass = weight ÷ \(g\).
Mass \(= \dfrac{120}{10} = 12 \, \text{kg}\).

(b)(i) Frayed cables

Fig. 6.2 shows the cable insulation is worn away/frayed, exposing the wires underneath.

(b)(ii) Danger of electrocution or short circuit

Exposed wires from frayed cables can be touched directly, risking electric shock.
Exposed wires may also touch each other and cause a short circuit, which can start a fire.

(c)(i) The normal

Line XY is drawn perpendicular to the mirror at the point where the ray strikes it.
This line is called the normal, and angles of incidence/reflection are measured from it.

(c)(ii) Angle b

The angle of incidence is the angle between the incident ray and the normal, on the side of the incoming ray.
This corresponds to angle b in Fig. 6.3.

(c)(iii) The angle of incidence equals the angle of reflection

This is the law of reflection, which applies to all reflecting surfaces including plane mirrors.

Question 7

(a) Fig. 7.1 is a diagram of the alimentary canal and associated organs.
(i) Identify the letter in Fig. 7.1 that represents the part:
where egestion occurs ………………………….
where most absorption of food molecules occurs ………………………….
that releases food into the small intestine ………………………….
(ii) State the names of parts A and C in Fig. 7.1.
(b) Circle the correct words in bold in the sentence to describe assimilation.
Assimilation is the movement of digested/insoluble food molecules into the cells/genes of the body where they are used.
(c) (i) The boxes on the left show principal sources of some nutrients. The boxes on the right show the names of some nutrients. Draw lines to link each principal source with the main nutrient it supplies.
(ii) List the chemical elements that make up carbohydrates.
(iii) Describe the importance of calcium in the diet.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic B7.3 — Digestion (Parts (a), (b))
• Topic B7.1 — Diet (Part (c))

▶️ Answer/Explanation

(a)(i) F (egestion); D (absorption); B (releases food into small intestine)

Egestion (removal of undigested waste) occurs at the anus/rectum, labelled F.
Most absorption occurs in the small intestine, labelled D.
The stomach, labelled B, releases food into the small intestine.

(a)(ii) A – liver; C – pancreas

Part A is the liver, which produces bile.
Part C is the pancreas, which produces digestive enzymes.

(b) digested and cells

Assimilation is the movement of digested food molecules (not insoluble ones) into the cells of the body, where they are used.

(c)(i)

Butter is a fatty food, so it links to fat.
Rice is a starchy food, so it links to carbohydrate.
Tuna fish is a protein-rich food, so it links to protein.

(c)(ii) Carbon, hydrogen, oxygen

Carbohydrates are made up of only these three elements, in the ratio typically seen in sugars and starches.

(c)(iii) Calcium strengthens bones and teeth

Calcium is an important mineral required for building strong bones and teeth.
A deficiency can lead to weak or brittle bones.

Question 8

(a) Aluminium is obtained from its ore. Aluminium ore is a finite resource, so conserving aluminium is important.
(i) Explain what is meant by the term finite resource.
(ii) State the name of the ore from which aluminium is extracted.
(b) Aluminium is a metal.
State two physical or chemical properties of aluminium that make it suitable for use as food containers. Explain your answers.
(c) (i) Aluminium is often used in alloys. State the meaning of the term alloy.
(ii) Table 8.1 shows the composition of elements by mass of \(100 \, \text{g}\) of an aluminium alloy.
Calculate the mass of aluminium in \(100 \, \text{g}\) of the alloy.
(iii) Identify the three transition elements listed in Table 8.1.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C9.2 — Uses of metals (Parts (a), (b))
• Topic C9.3 — Alloys and their properties (Part (c))

▶️ Answer/Explanation

(a)(i) A finite resource is one that is no longer being made, or is made extremely slowly

This means the resource will eventually run out, since it cannot be replenished at the rate it is used.

(a)(ii) Bauxite

Bauxite is the ore from which aluminium metal is extracted, usually by electrolysis.

(b) Unreactive/resists corrosion; low density

Aluminium is unreactive and resists corrosion, so food stored in it stays safe and uncontaminated.
Aluminium has a low density, so containers made from it are lightweight and easy to transport.
Aluminium is also malleable, allowing it to be shaped easily into thin sheets for containers.

(c)(i) An alloy is a mixture of two or more metals, or a metal and other elements

Mixing elements in this way often improves the properties of the pure metal, such as its strength.

(c)(ii) 83.8 g

Total mass of alloy \(= 100 \, \text{g}\).
Mass of aluminium \(= 100 – (1.3 + 0.6 + 1.1 + 2.3 + 10.9) = 100 – 16.2 = 83.8 \, \text{g}\).

(c)(iii) Copper, iron, nickel

These three elements listed in Table 8.1 are transition elements, found in the central block of the Periodic Table.
Aluminium, magnesium and silicon are not transition elements.

Question 9

(a) Table 9.1 shows the highest and lowest frequencies that five animals can hear.
(i) State which animals from Table 9.1 can hear sounds with a pitch higher than a rat can hear. Explain your answer.
(ii) A bat emits a high frequency sound.
State the range of frequencies emitted by a bat that a healthy human ear can hear.
(b) (i) A bat flies at a constant speed of \(40 \, \text{m/s}\).
Calculate the time taken by the bat to travel \(200 \, \text{m}\).
(ii) Bats and birds often fly into wind turbines and are killed.
State one other disadvantage of using wind turbines to generate electrical energy.
(iii) Wind energy is an example of a renewable energy source.
State one other renewable energy source.
(c) (i) Some bats are able to detect ultraviolet radiation. Ultraviolet radiation is part of the electromagnetic spectrum.
Fig. 9.1 shows an incomplete electromagnetic spectrum.
Write ultraviolet in the correct position in the electromagnetic spectrum.
(ii) State one danger of ultraviolet radiation to humans.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic B13.1 — Coordination and response (Part (a))
• Topic P1.2 — Motion (Part (b)(i))
• Topic P1.6.3 — Energy resources (Part (b)(ii)–(iii))
• Topic P3.3 — Electromagnetic spectrum (Part (c))

▶️ Answer/Explanation

(a)(i) Bat and dolphin

The rat’s highest frequency is \(76\,000 \, \text{Hz}\).
Pitch is determined by frequency, so any animal with a higher highest-frequency value can hear a higher pitch.
Bat \((200\,000 \, \text{Hz})\) and dolphin \((130\,000 \, \text{Hz})\) both exceed this value.

(a)(ii) Highest frequency 20,000 Hz; lowest frequency 2,000 Hz

Bats emit sound from \(2000\,\text{Hz}\) to \(200\,000\,\text{Hz}\).
The human ear can only detect up to about \(20\,000\,\text{Hz}\), so the audible range of the bat’s sound to humans is \(2000\,\text{Hz}\) to \(20\,000\,\text{Hz}\).

(b)(i) 5 s

Time = distance ÷ speed.
Time \(= \dfrac{200}{40} = 5 \, \text{s}\).

(b)(ii) Unreliable, as it depends on the wind blowing

Wind turbines cannot generate electricity when there is no wind, making supply inconsistent.

(b)(iii) HEP / solar / tidal / wave / geothermal

Any renewable energy source other than wind is acceptable, such as hydroelectric power or solar energy.

(c)(i) Ultraviolet sits between X-rays and visible light

The electromagnetic spectrum in order of decreasing frequency is: gamma rays, X-rays, ultraviolet, visible light, infrared, microwaves, radio waves.
Ultraviolet radiation is placed directly between X-rays and visible light.

(c)(ii) Skin cancer or sunburn

Excessive exposure to ultraviolet radiation damages skin cells, which can cause sunburn and increase the risk of skin cancer.

Question 10

(a) Fig. 10.1 is a diagram of the gas exchange system in humans.
State the names of the parts labelled A, B and C in Fig. 10.1.
(b) Describe three ways the composition of expired air is different from inspired air.
(c) Gases move across the gas exchange surface by diffusion.
Place ticks (✓) next to all the statements that correctly describe diffusion.
(d) Gas exchange also occurs in plants.
(i) State the name of the part of the leaf where water vapour exits.
(ii) State the term used to describe when water evaporates and then diffuses out of a leaf.
(iii) State two factors that increase the rate of water loss from a leaf.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic B11.1 — Gas exchange in humans (Parts (a)–(c))
• Topic B8.3 — Transpiration (Part (d))

▶️ Answer/Explanation

(a) A – trachea; B – bronchus; C – alveoli

The trachea (windpipe) leads into the bronchi, which branch into smaller tubes ending in the alveoli.
Gas exchange with the blood takes place at the alveoli.

(b) Expired air contains more carbon dioxide, less oxygen, and more water vapour

Oxygen is used up by the body during respiration, so expired air contains less of it than inspired air.
Carbon dioxide is produced by respiration, so expired air contains more of it.
Water vapour is added to the air as it passes through the moist respiratory passages, so expired air contains more water vapour.

(c)

Diffusion is the net movement of any particles (not only water) due to their random motion.
It occurs down a concentration gradient (from high to low concentration), not against it, and does not require energy from respiration.
It can occur across a cell membrane, such as at the alveoli or in plant leaves.

(d)(i) Stoma / stomata

Water vapour exits the leaf through small pores called stomata, usually located on the underside of the leaf.

(d)(ii) Transpiration

Transpiration is the term for the evaporation of water from inside the leaf followed by its diffusion out through the stomata.

(d)(iii) Increase in temperature; decrease in humidity

Higher temperature increases the rate of evaporation of water from leaf cells, speeding up transpiration.
Lower humidity increases the concentration gradient between the leaf and the air, speeding up diffusion of water vapour out of the leaf.

Question 11

(a) Methane, \(\text{CH}_4\), is the main constituent of a fossil fuel.
(i) State the name of this fossil fuel.
(ii) State the name of one other fossil fuel.
(iii) Methane is a greenhouse gas. State the name of one other common greenhouse gas.
(b) Complete Fig. 11.1 to show the structural formula of methane.
(c) (i) When methane is completely combusted in oxygen, carbon dioxide and water are produced.
Balance the symbol equation for this reaction.
\( \text{CH}_4 + \text{……………} \text{O}_2 \rightarrow \text{CO}_2 + \text{……………} \text{H}_2\text{O} \)
(ii) The combustion of methane is an exothermic reaction.
Describe what is observed during an exothermic reaction.
(d) (i) State which diagram from Fig. 11.2 shows the structural formula of an alcohol.
(ii) Describe the chemical test that distinguishes between A and B in Fig. 11.2.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C11.3 — Fuels (Part (a))
• Topic C11.1 — Formulas and terminology (Part (b))
• Topic C11.3 — Fuels (Part (c)(i)); Topic C5.1 — Exothermic and endothermic reactions (Part (c)(ii))
• Topic C11.6 — Alcohols; Topic C11.5 — Alkenes (Part (d))

▶️ Answer/Explanation

(a)(i) Natural gas

Methane is the main constituent of natural gas, a fossil fuel formed from the remains of ancient marine organisms.

(a)(ii) Coal or petroleum

Coal and petroleum (crude oil) are the other two main fossil fuels, alongside natural gas.

(a)(iii) Carbon dioxide

Carbon dioxide is another common greenhouse gas, alongside methane and water vapour.

(b)

Methane \(\text{CH}_4\) has one carbon atom bonded to four hydrogen atoms, arranged symmetrically around the central carbon.
Each C–H bond is a single covalent bond.

(c)(i) \(\text{CH}_4 + 2\text{O}_2 \rightarrow \text{CO}_2 + 2\text{H}_2\text{O}\)

There are 4 hydrogen atoms in methane, requiring \(2\text{H}_2\text{O}\) on the product side to balance them.
This gives 4 oxygen atoms needed on the product side (2 from \(\text{CO}_2\) and 2 from \(2\text{H}_2\text{O}\)), so \(2\text{O}_2\) is needed as reactant.

(c)(ii) Temperature rise

An exothermic reaction releases heat energy to the surroundings.
This is observed as an increase in temperature during the reaction.

(d)(i) C

Diagram C contains an –O–H group attached to the carbon chain, which is the functional group of an alcohol.
Diagrams A, B and D do not contain this group.

(d)(ii) Test: add aqueous bromine

Aqueous bromine is added to both A and B.
Result for A: no change, the solution stays orange, since A is a saturated compound with no C=C double bond.
Result for B: the solution decolorises (changes from orange to colourless), since B contains a C=C double bond typical of an alkene.

Question 12

Fig. 12.1 shows a refrigerator.
(a) (i) The refrigerator uses electrical energy to
  • power the electric motor which operates the cooler
  • light the lamp inside the refrigerator.
The electric motor and the lamp are connected in parallel.
The circuit symbol for a motor is
Complete the circuit diagram for the refrigerator shown in Fig. 12.2.
(ii) State the name of component X.
(iii) State the purpose of component X in this circuit.
(b) Food is kept in a refrigerator so that it stays fresh for longer.
Another way to preserve food is to treat it with \(\gamma\)-radiation.
\(\gamma\)-radiation is a form of ionising radiation.
State the name of one other form of ionising radiation.
(c) The volume of air in the refrigerator is \(0.25 \, \text{m}^3\).
The density of the air is \(1.28 \, \text{kg/m}^3\).
Calculate the mass of the air in the refrigerator in grams.
(d) Fig. 12.3 shows a liquid-in-glass thermometer.
The thermometer is used to measure the temperature inside the freezing compartment of the refrigerator. This temperature is \(-18\,^\circ\text{C}\).
Table 12.1 gives some information about four liquids.
(i) Identify all the liquids from Table 12.1 that are suitable for use in this thermometer.
(ii) State the physical property of the liquid in the thermometer that varies with temperature.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic P4.3.2 — Series and parallel circuits (Part (a))
• Topic P5.2.1 — Detection of radioactivity (Part (b))
• Topic P1.4 — Density (Part (c))
• Topic P2.2.1 — Thermal expansion of solids, liquids and gases (Part (d))

▶️ Answer/Explanation

(a)(i) Correct symbol for lamp; lamp and motor in parallel

The lamp should be drawn using the standard circle-with-cross circuit symbol.
The lamp and motor branches should each connect separately across the supply, forming a parallel arrangement.

(a)(ii) Fuse

Component X, shown in series in the main circuit, is a fuse.

(a)(iii) Protects the circuit

The fuse melts and breaks the circuit if the current becomes too large.
This prevents damage to the circuit components and reduces the risk of fire.

(b) Alpha, beta or X-rays

Any of these three types of radiation are also classified as ionising radiation, alongside gamma radiation.

(c) 320 g

Mass = density × volume.
Mass \(= 1.28 \times 0.25 = 0.32 \, \text{kg}\).
Converting to grams: \(0.32 \times 1000 = 320 \, \text{g}\).

(d)(i) Ethanol, mercury and methanol

A suitable thermometer liquid must remain liquid at \(-18\,^\circ\text{C}\), meaning its melting point must be below this temperature.
Ethanol \((-114\,^\circ\text{C})\), mercury \((-39\,^\circ\text{C})\) and methanol \((-98\,^\circ\text{C})\) all satisfy this, but water \((0\,^\circ\text{C})\) does not, since it would be frozen solid.

(d)(ii) Density (or volume)

As temperature increases, the liquid expands, changing its volume (and therefore its density).
This physical change is what allows the thermometer to indicate a temperature reading.

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