IB DP Chemistry - Reactivity 3.1 Proton transfer reactions - IB Style Questions For HL Paper 1A -FA 2025

Question

Which graph illustrates the titration curve produced when a strong acid is gradually added to a strong base?
▶️ Answer/Explanation

• A strong base initially has a high pH.
• When a strong acid is added, the pH drops sharply at the equivalence point.
• Graph C shows this typical steep decrease in pH for a strong acid–strong base titration.

Answer: (C)

Question

Which products are formed from the neutralization of nitric acid by calcium hydroxide?
(A) Calcium oxide and ammonia
(B) Calcium nitrate and water
(C) Calcium nitrate and ammonia
(D) Calcium nitrate and hydrogen
▶️ Answer/Explanation
Detailed solution

Neutralization occurs when an acid reacts with a base to produce a salt and water.
Nitric acid is \(HNO_3\) and calcium hydroxide is \(Ca(OH)_2\).
The balanced neutralization equation is:
\[2HNO_3(aq) + Ca(OH)_2(aq) \rightarrow Ca(NO_3)_2(aq) + 2H_2O(l)\]
The products are therefore calcium nitrate, \(Ca(NO_3)_2\), and water, \(H_2O\).
Answer: (B)

Question

What is the relationship between acid and base dissociation constants in a conjugate acid–base pair?
(A) \(K_a \times K_b = K_w\)
(B) \(\frac{K_a}{K_b} = K_w\)
(C) \(pK_a \times pK_b = pK_w\)
(D) \(\frac{pK_a}{pK_b} = pK_w\)
▶️ Answer/Explanation
Detailed solution

For any conjugate acid–base pair, the acid dissociation constant \((K_a)\) and base dissociation constant \((K_b)\) are related through the ion-product constant of water, \(K_w\).

The relationship is:
\[K_a \times K_b = K_w\]

Where:
K_a = acid dissociation constant
K_b = base dissociation constant
K_w = \(1.0 \times 10^{-14}\) at 25°C

Therefore, the correct answer is:
Answer: (A)

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