IB DP Chemistry - Structure 1.3 Electron configurations - IB Style Questions For HL Paper 1A -FA 2025

Question

Which of the following species contain the same number of outer-shell electrons?
The letters do not correspond to actual element symbols.
\(^{24}_{12}W^{2+}\) \(^{31}_{16}X^{-}\) \(^{45}_{21}Y^{2+}\) \(^{19}_{9}Z^{-}\)
(A) X and Y
(B) X and W
(C) Z and Y
(D) Z and W
▶️ Answer/Explanation
Detailed solution

Determine electron configuration for each:

  • W²⁺ (Z=12): Neutral W has 12e⁻ → W²⁺ has 10e⁻ → 1s² 2s² 2p⁶ (neon configuration) → 8 outer electrons
  • X⁻ (Z=16): Neutral X has 16e⁻ → X⁻ has 17e⁻ → 1s² 2s² 2p⁶ 3s² 3p⁵ (chlorine configuration) → 7 outer electrons
  • Y²⁺ (Z=21): Neutral Y has 21e⁻ → Y²⁺ has 19e⁻ → 1s² 2s² 2p⁶ 3s² 3p⁶ 4s¹ (potassium-like) → 1 outer electron
  • Z⁻ (Z=9): Neutral Z has 9e⁻ → Z⁻ has 10e⁻ → 1s² 2s² 2p⁶ (neon configuration) → 8 outer electrons

W²⁺ and Z⁻ both have 8 outer electrons (full octet).

Answer: (D)

Question

What is the maximum number of electrons that can occupy the energy level \(n = 4\)?
(A) \(8\)
(B) \(18\)
(C) \(32\)
(D) \(50\)
▶️ Answer/Explanation
Detailed solution

The maximum number of electrons in a given energy level \(n\) is given by the formula \(2n^2\).
For \(n = 4\):
\(2n^2 = 2(4)^2 = 2 \times 16 = 32\).
Therefore, the maximum number of electrons in the energy level \(n = 4\) is \(32\).
Answer: (C)

Question

Which of the following lists the sub-levels in order of increasing energy in the fourth energy level of an atom?
(A) \({f} < {d} < {p} < {s}\)
(B) \({p} < {d} < {f} < {s}\)
(C) \({d} < {f} < {p} < {s}\)
(D) \({s} < {p} < {d} < {f}\)
▶️ Answer/Explanation
Detailed solution

In the fourth energy level of an atom, the sub-levels increase in energy in the following order: \({s} < {p} < {d} < {f}\).

This is based on the general Aufbau principle, where the complexity of orbitals and the distance of electrons from the nucleus increase from s → p → d → f.

Therefore, the correct answer is:
Answer: (D)

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