IB DP Chemistry - Structure 2.1 The ionic model - IB Style Questions For HL Paper 1A -FA 2025

Question

Which row gives the correct formula and electron configuration of the species present in calcium nitride?
FormulaElectron configuration of the Ca speciesElectron configuration of the N species
A.        Ca2N3[Ar][Ne]
B.         Ca2N3[Ar] 4s2[He] 2s2 2p3
C.        Ca2N2[Ar] 4s2[He] 2s2 2p3
D.       Ca2N2[Ar][Ne]
▶️ Answer/Explanation
Detailed solution

Calcium nitride:

  • Formula: Ca3N2 (Ca2+ and N3−)
  • Ca2+: loses 2 electrons → [Ar] configuration (without 4s2)
  • N3−: gains 3 electrons → [Ne] configuration (1s2 2s2 2p6)

Answer: (D) – Ca2N2 with [Ar] and [Ne] configurations

Note: While the exact formula should be Ca3N2, among the given options, (D) has the correct electron configurations for the ionic species.

Question

Which compounds have an ionic lattice structure in the solid state?
I.    Silicon dioxide
II.   Sodium fluoride
III.  Ammonium nitrate
A. I and II only
B. I and III only
C. II and III only
D. I, II and III
▶️ Answer/Explanation
Detailed solution

An ionic lattice in the solid state is made up of positively and negatively charged ions held together by strong electrostatic forces.

Silicon dioxide (SiO₂) has a giant covalent (network) structure, not an ionic lattice, so I is not ionic.
Sodium fluoride (NaF) is made of Na⁺ and F⁻ ions arranged in an ionic lattice, so II is ionic.
Ammonium nitrate (NH₄NO₃) is composed of the ions NH₄⁺ and NO₃⁻, which also form an ionic lattice in the solid state, so III is ionic.

Therefore, the compounds with ionic lattice structures are II and III only.
Answer: (C)

Question

The table shows some physical properties of a certain substance.
Melting point / °CElectrical conductivity
 MoltenSolid
1414poorpoor
Based on this information, what is the most likely structure of the substance?
A. Network covalent
B. Polar covalent molecule
C. Ionic lattice
D. Metallic lattice

▶️ Answer/Explanation

Correct Answer: A. Network covalent

• A very high melting point (1414 °C) suggests a giant covalent structure.
• Poor electrical conductivity in both molten and solid states is also characteristic of network covalent solids.
• Ionic compounds would conduct electricity when molten, and metals conduct in solid form—so these are eliminated.

✔️ Therefore, the substance is most likely **network covalent**.

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