IB DP Chemistry: Topic 11.1 Uncertainties and errors in measurement and results: Study Notes

11.1 Uncertainties and errors in measurement and results

Essential idea:

All measurement has a limit of precision and accuracy, and this must be taken into account when evaluating experimental results.

Understandings:

  • Qualitative data includes all non-numerical information obtained from observations not from measurement.
  • Quantitative data are obtained from measurements, and are always associated with random errors/uncertainties, determined by the apparatus, and by human limitations such as reaction times.
  • Propagation of random errors in data processing shows the impact of the uncertainties on the final result.
  • Experimental design and procedure usually lead to systematic errors in measurement, which cause a deviation in a particular direction.
  • Repeat trials and measurements will reduce random errors but not systematic errors.

Applications and Skills:

  • Distinction between random errors and systematic errors.
  • Record uncertainties in all measurements as a range (+) to an appropriate precision.
  • Discussion of ways to reduce uncertainties in an experiment.
  • Propagation of uncertainties in processed data, including the use of percentage uncertainties.
  • Discussion of systematic errors in all experimental work, their impact on the results and how they can be reduced.
  • Estimation of whether a particular source of error is likely to have a major or minor effect on the final result.
  • Calculation of percentage error when the experimental result can be compared with a theoretical or accepted result.
  • Distinction between accuracy and precision in evaluating results.

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