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IB MYP 4-5 Chemistry -Acid + base, metal, or carbonate reactions- Study Notes - New Syllabus

IB MYP 4-5 Chemistry -Acid + base, metal, or carbonate reactions- Study Notes

Key Concepts

  •  Reactions of Acids with Bases, Metals, and Carbonates

IB MYP 4-5 Chemistry Study Notes – All topics

 Reactions of Acids with Bases, Metals, and Carbonates

 Reactions of Acids with Bases, Metals, and Carbonates

Acids react with different classes of substances — bases, metals, and carbonates — in characteristic ways. These reactions help identify acids and are used widely in laboratory and industrial chemistry.

Reaction of Acid with Base — Neutralization

General Equation:

\( \mathrm{Acid + Base \rightarrow Salt + Water} \)

Ionic Equation:

\( \mathrm{H^+(aq) + OH^-(aq) \rightarrow H_2O(l)} \)

Explanation:

  • Acids provide hydrogen ions \( \mathrm{(H^+)} \), bases provide hydroxide ions \( \mathrm{(OH^-)} \).
  • These ions combine to form water, while the remaining ions form a salt.

Example: \( \mathrm{HCl + NaOH \rightarrow NaCl + H_2O} \)

Reaction of Acid with Metal

 

General Equation:

\( \mathrm{Acid + Metal \rightarrow Salt + Hydrogen\ gas} \)

Explanation:

  • Metals above hydrogen in the reactivity series react with acids.
  • Hydrogen gas is released during the reaction.
  • Salt formed depends on the acid and the metal used.

Examples:

  • \( \mathrm{Mg + 2HCl \rightarrow MgCl_2 + H_2} \)
  • \( \mathrm{Zn + H_2SO_4 \rightarrow ZnSO_4 + H_2} \)

Observation: Effervescence (bubbling) occurs due to hydrogen gas production.

Reaction of Acid with Carbonate (or Hydrogen Carbonate)

General Equation:

\( \mathrm{Acid + Carbonate \rightarrow Salt + Water + Carbon\ dioxide} \)

or

\( \mathrm{Acid + Hydrogen\ carbonate \rightarrow Salt + Water + Carbon\ dioxide} \)

Explanation:

  • Acid reacts with a carbonate or bicarbonate to produce carbon dioxide gas, which causes effervescence.
  • The reaction is used as a test for carbonates — gas turns limewater milky.

Examples:

  • \( \mathrm{CaCO_3 + 2HCl \rightarrow CaCl_2 + H_2O + CO_2} \)
  • \( \mathrm{NaHCO_3 + HCl \rightarrow NaCl + H_2O + CO_2} \)

Acid Reactions

Type of Substance Reacting with AcidGeneral ReactionProducts FormedExample Equation
Base (Alkali)Acid + Base → Salt + WaterNeutralization product\( \mathrm{HCl + NaOH \rightarrow NaCl + H_2O} \)
MetalAcid + Metal → Salt + Hydrogen gasSalt + \( \mathrm{H_2} \)\( \mathrm{Zn + H_2SO_4 \rightarrow ZnSO_4 + H_2} \)
CarbonateAcid + Carbonate → Salt + Water + CO₂Salt + \( \mathrm{CO_2} + \mathrm{H_2O} \)\( \mathrm{CaCO_3 + 2HCl \rightarrow CaCl_2 + H_2O + CO_2} \)

Laboratory Observations for Each Reaction

Reaction TypeObservable EffectGas ProducedGas Test
Acid + BaseTemperature rises slightlyNone
Acid + MetalEffervescence / bubblingHydrogenPops with a lighted splint
Acid + CarbonateFizzing / gas bubblesCarbon dioxideTurns limewater milky

Example

Write a balanced equation for the reaction between hydrochloric acid and magnesium.

▶️ Answer / Explanation

Step 1: Magnesium reacts with acid to produce hydrogen gas and salt.

Step 2: \( \mathrm{Mg + 2HCl \rightarrow MgCl_2 + H_2} \)

Final Answer: Magnesium chloride and hydrogen gas are formed, with visible effervescence.

Example 

Describe the reaction between sulfuric acid and sodium carbonate. What test confirms the gas produced?

▶️ Answer / Explanation

Step 1: \( \mathrm{Na_2CO_3 + H_2SO_4 \rightarrow Na_2SO_4 + H_2O + CO_2} \)

Step 2: Effervescence due to carbon dioxide gas.

Step 3: Passing gas through limewater turns it milky — confirms \( \mathrm{CO_2} \).

Final Answer: Sodium sulfate, water, and carbon dioxide are formed.

Example 

A student mixes nitric acid with calcium hydroxide and collects the resulting solution. Identify the salt formed and explain how you could confirm neutralization.

▶️ Answer / Explanation

Step 1: Reaction: \( \mathrm{2HNO_3 + Ca(OH)_2 \rightarrow Ca(NO_3)_2 + 2H_2O} \)

Step 2: Salt formed is calcium nitrate.

Step 3: Neutralization can be confirmed using litmus — final solution is nearly neutral (pH ≈ 7).

Final Answer: Calcium nitrate is formed; no effervescence; temperature rise indicates exothermic neutralization.

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