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IBDP Chemistry -Structure 1.3 Electron configurations- IB Style Questions For SL Paper 1A -FA 2025

Question

Which pair of the following species has the same number of outer-shell (valence) electrons? The letters do not correspond to real element symbols.
\({}^{24}_{12}W^{2+} \quad {}^{31}_{16}X^{-} \quad {}^{45}_{21}Y^{2+} \quad {}^{19}_{9}Z^{-}\)
A. \(X\) and \(Y\)
B. \(X\) and \(W\)
C. \(Z\) and \(Y\)
D. \(Z\) and \(W\)
▶️ Answer/Explanation
Detailed solution

1. Find the total number of electrons for each species:
\(W^{2+}:\) atomic number \(12 \Rightarrow\) electrons \(= 12 – 2 = 10\).
\(X^{-}:\) atomic number \(16 \Rightarrow\) electrons \(= 16 + 1 = 17\).
\(Y^{2+}:\) atomic number \(21 \Rightarrow\) electrons \(= 21 – 2 = 19\).
\(Z^{-}:\) atomic number \(9 \Rightarrow\) electrons \(= 9 + 1 = 10\).

2. Compare electron arrangements and outer electrons:
Species with \(10\) electrons have the same configuration as neon: \(2, 8\), so they each have \(8\) outer (valence) electrons.
Thus \(W^{2+}\) and \(Z^{-}\) both possess \(8\) valence electrons.
The species with \(17\) and \(19\) electrons have different outer-electron counts.

Answer: (D)

Question

What is the maximum number of electrons in energy level \(n = 4\)?
A. \(\;8\)
B. \(\;18\)
C. \(\;32\)
D. \(\;50\)
▶️ Answer/Explanation
Detailed solution

The maximum number of electrons that can occupy a principal energy level \(n\) is given by: \[ \text{max electrons} = 2n^{2} \]

For \(n = 4\): \[ \text{max electrons} = 2 \times 4^{2} = 2 \times 16 = 32 \]

Therefore, the maximum number of electrons in energy level \(n = 4\) is \(\,32\), which corresponds to option C.

Answer: (C)

Question

What is the correct ground state electron orbital configuration for \(2s^2 2p^2\)?

▶️ Answer/Explanation
Detailed solution

The configuration \(2s^2 2p^2\) corresponds to carbon. The \(2s\) orbital contains a paired set of electrons: \[ 2s: \uparrow\downarrow \]

The \(2p\) orbitals each receive one electron before any pairing occurs, following Hund’s rule: \[ 2p: \uparrow\ \ \uparrow\ \ \Box \]

This corresponds exactly to option A.

Answer: (A)

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