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IBDP Chemistry - Structure 2.1 The ionic model- IB Style Questions For SL Paper 1A - FA 2025

Question

Which row provides the correct formula and electron configuration of the ions present in calcium nitride?
 FormulaElectron config of Ca speciesElectron config of N species
A\(Ca_{2}N_{3}\)[Ar][Ne]
B\(Ca_{2}N_{3}\)\(4s^2\) [Ar][He] \(2s^2 2p^3\)
C\(Ca_{3}N_{2}\)[Ar] \(4s^2\)[He] \(2s^2 2p^3\)
D\(Ca_{3}N_{2}\)[Ar][Ne]
▶️ Answer/Explanation
Detailed solution

1. Determine Ionic Charges:

  • Calcium (Group 2) forms \(Ca^{2+}\) ions.
  • Nitrogen (Group 15) forms \(N^{3-}\) ions.

2. Determine Formula:
To balance charges: \(3 \times (+2) + 2 \times (-3) = 0\). The formula is \(Ca_{3}N_{2}\). This eliminates A and B.

3. Determine Electron Configurations of Ions:

  • \(Ca^{2+}\): Calcium (\([Ar]4s^2\)) loses 2 electrons \(\rightarrow\) \([Ar]\).
  • \(N^{3-}\): Nitrogen (\([He]2s^22p^3\)) gains 3 electrons \(\rightarrow\) \([He]2s^22p^6\), which is isoelectronic with Neon \([Ne]\).

4. Match to Options:
Formula \(Ca_{3}N_{2}\), Ca species \([Ar]\), N species \([Ne]\).
Answer: (D)

Question

How many electrons will be gained or lost when the element with electron configuration \(1s^{2}\,2s^{2}\,2p^{3}\) forms an ionic bond?
A. Two electrons lost
B. Two electrons gained
C. Three electrons lost
D. Three electrons gained
▶️ Answer/Explanation
Detailed solution

The configuration \(1s^{2}\,2s^{2}\,2p^{3}\) corresponds to an atom with \[ 2 + 2 + 3 = 7 \] electrons (nitrogen). Its valence-shell configuration is \[ 2s^{2}\,2p^{3}, \] which gives \(5\) valence electrons.

To achieve a stable octet (\(8\) valence electrons), the atom will gain: \[ 8 – 5 = 3 \text{ electrons}. \]

Therefore, when forming an ionic bond, this element gains three electrons.

Answer: (D)

Question

Which substance is likely to have an ionic lattice structure at \(298\ \text{K}\) and \(100\ \text{kPa\)?
 Melting pointConducts electricity in a liquid state?
Alowyes
Blowno
Chighno
Dhighyes
▶️ Answer/Explanation
Detailed solution

Ionic compounds consist of positive and negative ions held together by strong electrostatic attractions in an ionic lattice. These strong forces give ionic substances:

  • High melting points (a lot of energy is needed to break the lattice).
  • Electrical conductivity in the liquid (molten) state, because ions become mobile and can carry charge.

Among the options, only substance D has both a high melting point and conducts electricity in the liquid state, matching the typical properties of an ionic lattice.

Answer: (D)

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