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IB DP Chemistry – S1.3.3 Main energy levels – Study Notes

IB DP Chemistry - S1.3.3 Main energy levels- Study Notes - New Syllabus - 2026, 2027 & 2028

IB DP Chemistry – S1.3.3 Main energy levels – Study Notes – New Syllabus

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Structure 1.3.3 — Main Energy Levels and Electron Capacity

Structure 1.3.3 — Main Energy Levels and Electron Capacity

Main Energy Levels (Shells)

Electrons in an atom are arranged in energy levels or shells. These levels are represented by the principal quantum number \( n \), where:

  • \( n = 1 \) is the first (lowest) energy level
  • \( n = 2 \) is the second energy level, and so on

 

Maximum Number of Electrons in an Energy Level:

The number of electrons a main energy level can hold is given by the formula:

\( \text{Maximum electrons} = 2n^2 \)

Principal Quantum Number (n)ShellMaximum Number of ElectronsElectron Capacity Formula
1K2\( 2 \times 1^2 = 2 \)
2L8\( 2 \times 2^2 = 8 \)
3M18\( 2 \times 3^2 = 18 \)
4N32\( 2 \times 4^2 = 32 \)

Note:

  • While the formula gives the theoretical maximum number of electrons per level, actual electron configurations depend on sublevel energies (s, p, d, f).
  • This concept is foundational to the understanding of electron arrangements in atoms and periodicity.

Example

Calculate the maximum number of electrons that can be held in the third main energy level.

▶️Answer/Explanation

The third energy level corresponds to \( n = 3 \).

Use the formula \( 2n^2 \):

\( 2 \times 3^2 = 2 \times 9 = 18 \)

Answer: 18 electrons

Example

An atom has a total of 10 electrons. Deduce the energy levels that are occupied and how many electrons are in each.

▶️Answer/Explanation

Use the capacity of each level in sequence:

  • 1st level (n = 1): max 2 electrons → fill this first → 2 electrons
  • 2nd level (n = 2): max 8 electrons → remaining 8 electrons
  • Total = 2 + 8 = 10 electrons → no need for 3rd level

Answer: 1st level: 2 e⁻, 2nd level: 8 e⁻

Example

What is the minimum number of energy levels needed to accommodate 30 electrons in an atom?

▶️Answer/Explanation

Use energy level capacities cumulatively:

  • n = 1 → 2 electrons (total so far: 2)
  • n = 2 → 8 electrons (total: 10)
  • n = 3 → 18 electrons (total: 28)
  • n = 4 → required for remaining 2 electrons → total now 30

Answer: 4 energy levels are needed

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