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CIE iGCSE Co-Ordinated Science C2.4 Ions and ionic bonds Exam Style Questions Paper 2

Question

The formula of an ammonium ion is \(\text{NH}_4^+\).

The formula of a phosphate ion is \(\text{PO}_4^{3-}\).

What is the formula of ammonium phosphate?

A. \((\text{NH}_4)_3\text{PO}_4\)
B. \((\text{NH}_4)_2\text{PO}_4\)
C. \(\text{NH}_4\text{PO}_4\)
D. \(\text{NH}_4(\text{PO}_4)_3\)

▶️ Answer/Explanation
The ammonium ion has a charge of \(+1\) and the phosphate ion has a charge of \(-3\); to achieve electrical neutrality, 3 ammonium ions are needed for every 1 phosphate ion.
Therefore the formula is \((\text{NH}_4)_3\text{PO}_4\), giving a total charge of \(3(+1) + (-3) = 0\).
Answer: (A)

Question

Which statement describes the lattice structure of sodium chloride, \(\text{NaCl}\)?

A. It is a random arrangement of equal numbers of sodium atoms and chlorine atoms.
B. It is a random arrangement of equal numbers of sodium ions and chloride ions.
C. It is a regular arrangement of alternating sodium atoms and chlorine atoms.
D. It is a regular arrangement of alternating sodium ions and chloride ions.

▶️ Answer/Explanation
Sodium chloride is formed by ionic bonding, in which sodium atoms transfer electrons to chlorine atoms, forming \(\text{Na}^+\) and \(\text{Cl}^-\) ions, not neutral atoms.
These oppositely charged ions are held together by strong electrostatic forces in a giant lattice, arranged in a highly regular, repeating pattern rather than randomly.
So the structure consists of a regular, alternating arrangement of sodium ions and chloride ions.
Answer: (D)

Question

Which statement about ions is not correct?

A. Atoms form ions by gaining or losing electrons.
B. Ions are formed by non-metal atoms only when they lose electrons.
C. Ions in a solid ionic compound form a lattice structure.
D. Ions with opposite charges attract each other.

▶️ Answer/Explanation
Non-metal atoms typically form ions by gaining electrons (to complete their outer shell), not by losing them.
Statement B has this backwards, so it is incorrect.
Statements A, C and D are all true descriptions of ion formation and behaviour.
Answer: (B)

Question

Sodium phosphate, \(\text{Na}_3\text{PO}_4\), contains sodium ions, \(\text{Na}^+\).

Aluminium sulfate, \(\text{Al}_2(\text{SO}_4)_3\), contains sulfate ions, \(\text{SO}_4^{2-}\).

What is the formula of aluminium phosphate?

A. \(\text{AlPO}_4\)
B. \(\text{Al(PO}_4)_2\)
C. \(\text{Al}_2(\text{PO}_4)_3\)
D. \(\text{Al}_3(\text{PO}_4)_2\)

▶️ Answer/Explanation
Since \(\text{Na}_3\text{PO}_4\) balances three \(\text{Na}^+\) ions, the phosphate ion must carry a charge of \(\text{PO}_4^{3-}\).
Aluminium ions carry a charge of \(\text{Al}^{3+}\), deduced from \(\text{Al}_2(\text{SO}_4)_3\) balancing two \(\text{Al}^{3+}\) against three \(\text{SO}_4^{2-}\).
Since \(\text{Al}^{3+}\) and \(\text{PO}_4^{3-}\) have equal and opposite charges, they combine in a 1:1 ratio, giving the formula \(\text{AlPO}_4\).
Answer: (A)

Question

The bonding in potassium iodide is ionic.
Which row describes the potassium iodide lattice structure?

▶️Answer/Explanation

Ans: C

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