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CIE iGCSE Co-Ordinated Science C2.5 Simple molecules and covalent bonds Exam Style Questions Paper 3

Question

(a) The formulae of six gases found in the air are shown.
CO     CO₂     He     H₂O     N₂     O₂
Using these formulae:
(i) State the formula for a monatomic gas. 
(ii) State the formula for a toxic gas. 
(iii) State the formula for the gas that makes up 78% of clean dry air.
(iv) State the formula for an element. 
(v) State the formulae for the two substances that are needed to cause iron to rust.
(b) Hydrogen chloride is a gas.
Complete the dot-and-cross diagram in Fig. 5.1 to show the electron arrangement in a molecule of hydrogen chloride.
Draw outer shell electrons only.
(c) Hydrogen chloride dissolves in water to make dilute hydrochloric acid.
Describe the effect of dilute hydrochloric acid on blue litmus indicator.
(d) State the names of the two gaseous elements used in a fuel cell to produce electricity.

Most-appropriate topic codes (Cambridge IGCSE Coordinated Sciences 0654):

• Topic C10.2 — Air quality and climate (Part (a)(i)-(iv))
• Topic C9.5 — Corrosion of metals (Part (a)(v))
• Topic C2.5 — Simple molecules and covalent bonds (Part (b))
• Topic C7.1 — Characteristic properties of acids (Part (c))
• Topic C4.2 — Hydrogen-oxygen fuel cells (Part (d))

▶️ Answer/Explanation

(a)(i) He
Helium (He) is a monatomic gas because it consists of single atoms rather than molecules. It is a noble gas with a full outer electron shell.

(a)(ii) CO
Carbon monoxide (CO) is a toxic gas produced by incomplete combustion. It binds to haemoglobin in red blood cells, preventing oxygen transport.

(a)(iii) N₂
Nitrogen (N₂) makes up approximately 78% of clean, dry air. It is an inert gas at normal temperatures.

(a)(iv) He or N₂ or O₂
Elements are substances that contain only one type of atom. He, N₂, and O₂ are all elements, while CO, CO₂, and H₂O are compounds.

(a)(v) O₂ and H₂O
Rusting of iron requires both oxygen (O₂) and water (H₂O). These react with iron to form hydrated iron(III) oxide.

(b) Shared pair correct; all else correct
In HCl, hydrogen shares one electron with chlorine to complete both their outer shells. The dot-and-cross diagram should show one shared pair of electrons.

(c) turns red
Dilute hydrochloric acid is acidic. Acids turn blue litmus paper red, indicating a pH below 7.

(d) hydrogen; oxygen
A hydrogen-oxygen fuel cell uses hydrogen and oxygen as reactants. The chemical energy is converted directly into electrical energy with water as the only product.

Question

(a) Ethanol has the formula \(\text{C}_2\text{H}_5\text{OH}\).
(i) Explain why ethanol is not a hydrocarbon.
(ii) Ethanol is used in alcoholic drinks. State one other use of ethanol.
(iii) Draw the displayed formula of ethanol.
(iv) Determine the relative molecular mass, \(M_r\), of ethanol.
\([A_r: \text{C} = 12; \text{H} = 1; \text{O} = 16]\)
(b) Carbon dioxide and water are made during the complete combustion of ethanol.
(i) State one adverse effect of higher levels of carbon dioxide in the atmosphere.
(ii) Describe a chemical test for water. State the colour change observed.
(iii) Complete the dot-and-cross diagram in Fig. 6.1 to show the arrangement of electrons in a molecule of water. Draw the outer-shell electrons only.

Topic codes:

• Topic C11.2 — Naming organic compounds (Part (a)(iii))
• Topic C11.6 — Alcohols (Part (a)(i), (a)(ii) & (b))
• Topic C3.2 — Relative masses of atoms and molecules (Part (a)(iv))
• Topic C10.2 — Air quality and climate (Part (b)(i))
• Topic C10.1 — Water (Part (b)(ii))
• Topic C2.5 — Simple molecules and covalent bonds (Part (b)(iii))

▶️ Answer/Explanation

(a)(i) Hydrocarbons only contain carbon and hydrogen.
Ethanol contains carbon, hydrogen, and oxygen atoms. The presence of oxygen means it is not a hydrocarbon. Hydrocarbons are compounds that contain only carbon and hydrogen atoms.

(a)(ii) Solvent or fuel
Ethanol is commonly used as a solvent in manufacturing and as a fuel (e.g., in alcoholic drinks, as a fuel additive in petrol, or as a biofuel).

(a)(iii) Displayed formula of ethanol:

The displayed formula shows all the atoms and all the bonds in the molecule. Each line represents a covalent bond (shared pair of electrons).

(a)(iv) \(M_r = 46\)
Calculation: \((2 \times 12) + (6 \times 1) + (1 \times 16) = 24 + 6 + 16 = 46\)
Ethanol has 2 carbon atoms, 6 hydrogen atoms (5 from C₂H₅ and 1 from OH), and 1 oxygen atom.

(b)(i) Increased global warming / climate change
Carbon dioxide is a greenhouse gas that traps heat in the atmosphere. Higher levels of CO₂ lead to enhanced greenhouse effect, causing global warming and climate change.

(b)(ii) Anhydrous copper(II) sulfate: white to blue
Test: Add anhydrous copper(II) sulfate (white powder) to the sample. If water is present, it turns blue because copper(II) sulfate forms hydrated copper(II) sulfate (CuSO₄·5H₂O).

Alternative test: Anhydrous cobalt(II) chloride (blue) turns pink in the presence of water.

(b)(iii) Dot-and-cross diagram for water (\(\text{H}_2\text{O}\)):

In a water molecule, the oxygen atom shares one electron with each of the two hydrogen atoms, forming two single covalent bonds. Oxygen has 6 outer-shell electrons, and each hydrogen has 1 outer-shell electron. Each shared pair of electrons is drawn as a cross (×) for one atom and a dot (•) for the other. Oxygen also has two lone pairs of electrons (not involved in bonding).

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