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CIE iGCSE Co-Ordinated Science C4.2 Hydrogen–oxygen fuel cells Exam Style Questions Paper 4

Question

Hydrogen-oxygen fuel cells use hydrogen and oxygen to produce electricity.
(a) The reactions at the electrodes in a hydrogen-oxygen fuel cell are shown.
anode: \(H_2 \rightarrow 2H^+ + 2e^-\)
cathode: \(4H^+ + O_2 + 4e^- \rightarrow 2H_2O\)
(i) State the name of the only chemical product in a hydrogen-oxygen fuel cell. ______
(ii) Explain why the reaction between hydrogen and oxygen in a fuel cell involves oxidation. ______
(b) Table 6.1 shows information about using a hydrogen-oxygen fuel cell and a petrol engine for powering cars.
Suggest which fuel would be most suitable to power a car. Explain your answer.
(c) Oxides of nitrogen are formed in petrol car engines.
(i) State one adverse effect of oxides of nitrogen.
(ii) Explain how oxides of nitrogen form in petrol car engines.
(iii) Oxides of nitrogen and carbon monoxide are removed from a car engine by a catalytic converter.
Complete the balanced symbol equation for the reaction that takes place.
2CO + 2NO → ______ + ______

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C4.2 — Hydrogen-oxygen fuel cells
• Topic C10.2 — Air quality and climate

▶️ Answer/Explanation

(a)(i) water
The only product formed in a hydrogen-oxygen fuel cell is water, making it an environmentally friendly energy source.

(a)(ii) loss of electrons (from hydrogen)
Oxidation is defined as the loss of electrons. At the anode, hydrogen atoms lose electrons to form protons, so they are oxidised.

(b)

Any three from:

Hydrogen-oxygen fuel cell:

  • cheaper (than petrol) to refill
  • short refuelling time
  • good range
  • no pollution

OR

Petrol engine:

  • high availability / excellent availability
  • quicker refuelling
  • longer range (than hydrogen-oxygen)

The most suitable fuel depends on the criteria prioritised. Hydrogen-oxygen fuel cells produce no pollution but have limited availability, while petrol engines have excellent availability and slightly longer range but produce harmful emissions.

(c)(i) acid rain / respiratory problems
Oxides of nitrogen dissolve in rainwater to form acid rain, which damages buildings, soil, and aquatic ecosystems. They also irritate the respiratory system.

(c)(ii) nitrogen reacts with oxygen ; at high temperature (inside a car engine)
The high temperatures and pressures in car engines cause atmospheric nitrogen and oxygen to react, forming nitrogen oxides.

(c)(iii) 2CO + 2NO → 2CO₂ + N₂
In catalytic converters, carbon monoxide reduces nitrogen oxides, producing harmless carbon dioxide and nitrogen gas. This prevents toxic gases from being released into the atmosphere.

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