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CIE iGCSE Co-Ordinated Science C8.1 Arrangement of elements Exam Style Questions Paper 3

Question

(a) The Periodic Table of elements shows the symbols of all the chemical elements. Complete the sentences about the Periodic Table.
The elements are listed in order of their ……………….. number.
Moving from left to right across the Periodic Table, the elements become ……………….. metallic.
The metals in the middle of the Periodic Table include copper and iron. These metals form coloured compounds and are known as the ……………….. elements.
(b) Fig. 5.1 shows the position of 10 elements in part of the Periodic Table. The letters used are not the symbols of the elements.
Fig 5.1 Partial Periodic Table with letters
Use the letters of the elements given in Fig. 5.1 to identify:
(i)   one element that is a diatomic gas at room temperature   
(ii)   one element that is a solid at room temperature   
(iii)   one element that is an alkali metal   
(iv)   one element that is a noble gas   
(v)   the most reactive metal   
(vi)   the most reactive halogen 

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C2.2 — Atomic structure and the Periodic Table (Part (a))
• Topic C8.1 — Arrangement of elements (Part (b)(i) & (b)(ii))
• Topic C8.2 — Group I properties (Part (b)(iii) & (b)(v))
• Topic C8.3 — Group VII properties (Part (b)(vi))
• Topic C8.5 — Noble gases (Part (b)(iv))

▶️ Answer/Explanation

(a)
The elements are listed in order of their proton / atomic number.
Moving from left to right across the Periodic Table, the elements become less metallic.
These metals form coloured compounds and are known as the transition elements.
As you move across a period, the increasing number of outer-shell electrons makes it progressively harder for atoms to lose electrons and behave as metals. Transition elements sit in the central block of the Periodic Table and are characterised by variable oxidation states, catalytic behaviour, and the formation of coloured ions and compounds.

(b)(i)
S, T, or V
S represents hydrogen (Group I, Period 1), which exists as the diatomic molecule $\text{H}_2$ at room temperature. T and V are halogens (Group VII) which also exist as diatomic molecules — fluorine ($\text{F}_2$) and chlorine ($\text{Cl}_2$) respectively — and are gases at room temperature. Any one of these three letters is a correct answer.

(b)(ii)
P, Q, or R
P, Q, and R are all metals located in Group I (alkali metals), and metals are solids at room temperature. They represent lithium, sodium, and potassium respectively, all of which have melting points well above room temperature. Any one of these three letters is a correct answer.

(b)(iii)
P, Q, or R
Alkali metals occupy Group I of the Periodic Table, excluding hydrogen (S, Period 1) which is a non-metal. P (lithium, Period 2), Q (sodium, Period 3), and R (potassium, Period 4) are all alkali metals with one outer-shell electron, making them highly reactive. Any one of these three letters is a correct answer.

(b)(iv)
X, Y, or Z
Noble gases are found in Group VIII (Group 0) of the Periodic Table and have a completely full outer electron shell. X represents helium (Period 1), Y represents neon (Period 2), and Z represents argon (Period 3) — all of which are monatomic, colourless, and extremely unreactive gases at room temperature. Any one of these three letters is a correct answer.

(b)(v)
R
Reactivity of alkali metals increases down Group I as the outer electron is further from the nucleus and more easily lost. Among the Group I metals shown, R sits lowest in the group (Period 4 — potassium) and is therefore the most reactive metal in Fig. 5.1.

(b)(vi)
T
Reactivity of halogens decreases down Group VII as each successive element has a greater atomic radius, making it harder to attract an additional electron. T sits higher in the group (Period 2 — fluorine) than V (Period 3 — chlorine), making T the most reactive halogen shown in Fig. 5.1.

Question

(a) Gasoline/petrol reacts with oxygen in car engines making exhaust gases. This is an example of oxidation.
(i) State the meaning of oxidation.
(ii) Table 7.1 shows the composition of clean dry air and of exhaust gases.
Complete Table 7.1.
(iii) Use Table 7.1 to state the two products of the oxidation of gasoline/petrol.
(iv) Describe a chemical test for the presence of water in a sample of exhaust gases and state the observations for a positive result.
(b) Neon is another gas found in clean dry air.
Fig. 7.1 shows the electronic configuration of an atom of neon.
(i) Use Fig. 7.1 to explain why neon is found in Group VIII and Period 2 of the Periodic Table.
(ii) Use Fig. 7.1 to explain why neon is unreactive.
(c) Water at room temperature is a liquid. Water vapour in the air is a gas.
Name the change of state that occurs when:
  liquid water changes into water vapour
  water vapour changes into liquid water.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C6.3 — Redox (Part (a)(i))
• Topic C10.2 — Air quality and climate (Part (a)(ii) & (a)(iii))
• Topic C12.5 — Qualitative analysis (Part (a)(iv))
• Topic C8.1 — Arrangement of elements (Part (b)(i))
• Topic C8.5 — Noble gases (Part (b)(ii))
• Topic C1.1 — Solids, liquids and gases (Part (c))

▶️ Answer/Explanation

(a)(i) Oxidation is the gain of oxygen.

In this reaction, gasoline/petrol (a hydrocarbon) gains oxygen when it burns, forming carbon dioxide and water. Oxidation can also be defined as the loss of electrons or an increase in oxidation number, but at this level, “gain of oxygen” is the required definition.

(a)(ii) nitrogen: 78% ; oxygen: 21%

Clean dry air is approximately 78% nitrogen and 21% oxygen by volume. The remaining 1% consists of carbon dioxide, noble gases and other trace gases. These values are the standard composition of unpolluted air.

(a)(iii) 1. carbon dioxide ; 2. water

The complete combustion of hydrocarbons such as gasoline/petrol produces carbon dioxide and water as the main products. Table 7.1 shows that exhaust gases contain 13% carbon dioxide and 11% water vapour, confirming these as the oxidation products.

(a)(iv) Test using anhydrous copper(II) sulfate: white to blue

Alternative test: anhydrous cobalt(II) chloride: blue to pink.

Anhydrous copper(II) sulfate is a white powder that turns blue when water is present. Anhydrous cobalt(II) chloride is blue and turns pink in the presence of water. Both tests are used to detect water in a sample.

(b)(i) Group VIII – 8 electrons in the outer shell; Period 2 – electrons in 2 shells

Neon has 8 electrons in its outer shell (2,8 configuration), which places it in Group VIII (the noble gases). It has electrons arranged in 2 shells, so it is in Period 2 of the Periodic Table.

(b)(ii) Neon has a full outer shell of electrons.

A full outer shell (8 electrons) means neon has a stable electronic configuration. It does not need to gain, lose or share electrons to achieve stability, making it chemically unreactive.

(c) Evaporation ; Condensation

Evaporation is the change of state from liquid to gas (vapour) that occurs at the surface of a liquid. Condensation is the change of state from gas (vapour) to liquid when the gas cools down.

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