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CIE iGCSE Co-Ordinated Science C9.2 Uses of metals Water Exam Style Questions Paper 3

Question

(a) The list gives the names of seven elements:
calcium
carbon
copper
oxygen
nitrogen
potassium
sulfur
Answer the questions about these elements.
Each element may be used once, more than once or not at all.
State which element:
(i) is in Group I of the Periodic Table.
(ii) is in diamond.
(iii) is 78% of clean air.
(iv) gives a lilac flame test.
(v) is used in electroplating.
(vi) is used in the manufacture of sulfuric acid.
(b) Atoms contain protons, neutrons and electrons.
State which of these particles:
are in shells around the nucleus …………………………….
have a positive charge …………………………….
have the smallest mass. …………………………….

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C8.2 — Group I properties (Parts (a)(i), (a)(iv))
• Topic C2.1 — Elements, compounds and mixtures (Parts (a)(ii), (a)(iii), (a)(vi))
• Topic C9.2 — Uses of metals (Part (a)(v))
• Topic C2.2 — Atomic structure and the Periodic Table (Part (b))

▶️ Answer/Explanation

(a)(i) potassium

Potassium (K) has atomic number 19 with electronic structure 2.8.8.1, placing it in Group I (alkali metals).
From the given list, only potassium belongs to Group I of the Periodic Table.
Sodium is also a Group I element but is not in the list.

(a)(ii) carbon

Diamond is one of the allotropes of carbon, consisting of carbon atoms bonded in a giant covalent lattice.
Each carbon atom forms four covalent bonds in a tetrahedral arrangement, giving diamond its extreme hardness.
This is purely a carbon structure — no other element from the list is found in diamond.

(a)(iii) nitrogen

Clean (dry) air is composed of approximately 78% nitrogen \((\text{N}_2)\), 21% oxygen, and 1% other gases.
Nitrogen is the most abundant gas in the atmosphere by volume.
Oxygen makes up the second largest proportion at approximately 21%.

(a)(iv) potassium

The flame test for potassium produces a characteristic lilac (violet) colour.
Sodium gives yellow, calcium gives brick-red, and copper gives blue-green in flame tests.
Potassium’s lilac flame is often observed through blue cobalt glass to filter out any sodium contamination.

(a)(v) copper

Copper is the most commonly used metal in electroplating due to its excellent electrical conductivity and relatively low cost.
In electroplating, copper ions from a copper anode are deposited onto the cathode object.
The equation for copper electroplating involves \(\text{Cu}^{2+} + 2e^- \rightarrow \text{Cu}\) at the cathode.

(a)(vi) sulfur

Sulfur is a key raw material in the manufacture of sulfuric acid \((\text{H}_2\text{SO}_4)\) via the Contact Process.
In the Contact Process, sulfur is first burned to form sulfur dioxide: \(\text{S} + \text{O}_2 \rightarrow \text{SO}_2\).
This is then oxidised to sulfur trioxide and reacted with water to produce sulfuric acid.

(b) electrons; protons; electrons

Electrons occupy shells (energy levels) around the nucleus and are arranged in the order 2, 8, 8, … from the innermost shell.
Protons are found in the nucleus and carry a positive charge of \(+1\); neutrons are also in the nucleus but are neutral.
Electrons have negligible mass (approximately \(\frac{1}{1836}\) of a proton), making them the particles with the smallest mass.

Question

(a) Choose from the following substances to answer the questions.
Each substance may be used once, more than once or not at all.
aluminium  
chlorine  
copper(II) sulfate
  ethanol
  limestone
  sulfur
(i) Used as a chemical test for water.
(ii) Used as a solvent.
(iii) Used in aircraft parts.
(iv) Used in the manufacture of sulfuric acid.
(v) Used in the treatment of the water supply.
(vi) Used in the treatment of acidic soil.
(b) Sulfuric acid has the formula \( \text{H}_2\text{SO}_4 \).
(i) State the total number of atoms in one molecule of sulfuric acid.
(ii) State the total number of different elements found in one molecule of sulfuric acid.
(c) A student reacts magnesium with dilute sulfuric acid.
The equation for the reaction is shown.
\( \text{Mg(s)} + \text{H}_2\text{SO}_4\text{(aq)} \rightarrow \text{MgSO}_4\text{(aq)} + \text{H}_2\text{(g)} \)
(i) State the names of the two products of the reaction.
(ii) State the separation technique used by the student to remove any unreacted solid magnesium from the reaction mixture.

Most-appropriate topic codes (Cambridge IGCSE Co-ordinated Sciences 0654):

• Topic C10.1 — Water (Part (a)(i), (a)(v))
• Topic C9.2 — Uses of metals (Part (a)(iii))
• Topic C2.1/C3.1 — Elements, compounds and formulas (Part (a)(ii), (a)(iv), (a)(vi), (b))
• Topic C9.4 — Reactivity series (Part (c)(i), (c)(ii))

▶️ Answer/Explanation

(a)(i) copper(II) sulfate

Anhydrous (white) copper(II) sulfate turns blue when water is added.
This colour change is the standard chemical test for water.

(a)(ii) ethanol

Ethanol is a common organic solvent used to dissolve substances that do not dissolve well in water.

(a)(iii) aluminium

Aluminium has a low density and good strength, making it ideal for aircraft parts.

(a)(iv) sulfur

Sulfur is burned to produce sulfur dioxide, which is converted to sulfur trioxide and then sulfuric acid (Contact Process).

(a)(v) chlorine

Chlorine is added to water supplies to kill microbes (pathogens), making water safe to drink.

(a)(vi) limestone

Limestone (calcium carbonate) is a base; it neutralises excess acid in soil.

(b)(i) 7 atoms

Counting atoms in \( \text{H}_2\text{SO}_4 \): 2 hydrogen + 1 sulfur + 4 oxygen = 7 atoms in total.

(b)(ii) 3 different elements

The three different elements present are hydrogen (H), sulfur (S), and oxygen (O).

(c)(i) magnesium sulfate and hydrogen

From the equation, the two products formed are magnesium sulfate (\( \text{MgSO}_4 \)) and hydrogen gas (\( \text{H}_2 \)).

(c)(ii) filtration

Filtration separates the insoluble unreacted solid magnesium from the magnesium sulfate solution.
The solid remains as residue on the filter paper while the solution passes through as filtrate.

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