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CIE iGCSE Co-ordinated Sciences-C8.2 Group I properties- Study Notes- New Syllabus

CIE iGCSE Co-ordinated Sciences-C8.2 Group I properties – Study Notes

CIE iGCSE Co-ordinated Sciences-C8.2 Group I properties – Study Notes -CIE iGCSE Co-ordinated Sciences – per latest Syllabus.

Key Concepts:

CIE iGCSE Co-Ordinated Sciences-Concise Summary Notes- All Topics

Group I Alkali Metals: Lithium, Sodium, and Potassium

Group I elements, also called alkali metals, are metals found in the first column of the Periodic Table. They are characterised by having one valence electron in their outermost shell, which explains their chemical behaviour.

General Properties:

  • Relatively soft metals that can be cut with a knife.
  • Shiny when freshly cut but tarnish quickly in air due to reaction with oxygen.
  • Good conductors of heat and electricity.

Trends Down the Group:

  • Melting point: Decreases down the group. Lithium has the highest melting point, potassium the lowest. This is because metallic bonding becomes weaker as the size of the atom increases.
  • Density: Increases down the group. Larger atoms pack more mass into the metallic structure, making elements like potassium denser than lithium and sodium.
  • Reactivity with water: Increases down the group. Lithium reacts slowly with water, sodium more vigorously, and potassium reacts very vigorously, sometimes producing enough heat to ignite the hydrogen gas formed.

Example 

Compare the reaction of lithium, sodium, and potassium with water.

▶️Answer/Explanation

Lithium reacts slowly, producing bubbles of hydrogen and forming lithium hydroxide:
\( 2\text{Li} + 2\text{H}_2\text{O} \rightarrow 2\text{LiOH} + \text{H}_2 \)
Sodium reacts more vigorously, often melting into a small ball:
\( 2\text{Na} + 2\text{H}_2\text{O} \rightarrow 2\text{NaOH} + \text{H}_2 \)
Potassium reacts very vigorously, igniting the hydrogen gas formed:
\( 2\text{K} + 2\text{H}_2\text{O} \rightarrow 2\text{KOH} + \text{H}_2 \)

Example 

Explain the trend in melting points of lithium, sodium, and potassium.

▶️Answer/Explanation

Melting point decreases down the group because the metallic bonding becomes weaker. Larger atoms have more electron shells, so the single delocalised electron in the metallic lattice is further from the nucleus and less tightly held, weakening the bond between atoms.

Group I Alkali Metals: Lithium, Sodium, and Potassium

Group I elements, also called alkali metals, are metals found in the first column of the Periodic Table. They are characterised by having one valence electron in their outermost shell, which explains their chemical behaviour.

General Properties:

  • Relatively soft metals that can be cut with a knife.
  • Shiny when freshly cut but tarnish quickly in air due to reaction with oxygen.
  • Good conductors of heat and electricity.

Trends Down the Group:

  • Melting point: Decreases down the group. Lithium has the highest melting point, potassium the lowest. This is because metallic bonding becomes weaker as the size of the atom increases.
  • Density: Increases down the group. Larger atoms pack more mass into the metallic structure, making elements like potassium denser than lithium and sodium.
  • Reactivity with water: Increases down the group. Lithium reacts slowly with water, sodium more vigorously, and potassium reacts very vigorously, sometimes producing enough heat to ignite the hydrogen gas formed.

Example 

Compare the reaction of lithium, sodium, and potassium with water.

▶️Answer/Explanation

Lithium reacts slowly, producing bubbles of hydrogen and forming lithium hydroxide:
\( 2\text{Li} + 2\text{H}_2\text{O} \rightarrow 2\text{LiOH} + \text{H}_2 \)
Sodium reacts more vigorously, often melting into a small ball:
\( 2\text{Na} + 2\text{H}_2\text{O} \rightarrow 2\text{NaOH} + \text{H}_2 \)
Potassium reacts very vigorously, igniting the hydrogen gas formed:
\( 2\text{K} + 2\text{H}_2\text{O} \rightarrow 2\text{KOH} + \text{H}_2 \)

Example 

Explain the trend in melting points of lithium, sodium, and potassium.

▶️Answer/Explanation

Melting point decreases down the group because the metallic bonding becomes weaker. Larger atoms have more electron shells, so the single delocalised electron in the metallic lattice is further from the nucleus and less tightly held, weakening the bond between atoms.

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