Edexcel iGCSE Chemistry -1.34C Concentration Calculations- Study Notes- New Syllabus

Edexcel iGCSE Chemistry -1.34C Concentration Calculations- Study Notes- New syllabus

Edexcel iGCSE Chemistry -1.34C Concentration Calculations- Study Notes -Edexcel iGCSE Chemistry – per latest Syllabus.

Key Concepts:

1.34C understand how to carry out calculations involving amount of substance, volume and concentration (in mol/dm³) of solution

Edexcel iGCSE Chemistry -Concise Summary Notes- All Topics

1.34C Calculations Involving Amount of Substance, Volume and Concentration (mol/dm3)

In solution chemistry, you must be able to calculate relationships between:

  • Amount of substance (moles, \( n \))
  • Volume (dm3)
  • Concentration (mol/dm3)

Key Formula

\( c = \dfrac{n}{V} \)

Where:

\( c \) = concentration (mol/dm3)

\( n \) = number of moles (mol)

\( V \) = volume (dm3)

Rearrangements:

\( n = c \times V \)

\( V = \dfrac{n}{c} \)

Important Unit Conversion

Volume must be in dm3.

\( 1000 \text{ cm}^3 = 1 \text{ dm}^3 \)

To convert: divide cm3 by 1000

Link with Mass Calculations

If mass is given:

Step 1: \( n = \dfrac{m}{M_r} \)

Step 2: Use \( c = \dfrac{n}{V} \)

QuantitySymbolUnits
Moles\( n \)mol
Concentration\( c \)mol/dm3
Volume\( V \)dm3

Example 1 (Conceptual):

Why must volume be converted to dm3 before using the concentration formula?

▶️ Answer/Explanation

Concentration is measured in mol per dm3.

If volume is in cm3, the units will be incorrect.

Therefore, volume must be converted to dm3.

Example 2 (Numerical):

Calculate the concentration of a solution containing 0.50 mol of sodium chloride in 250 cm3 of solution.

▶️ Answer/Explanation

Step 1: Convert volume

\( 250 \div 1000 = 0.250 \text{ dm}^3 \)

Step 2: Use formula

\( c = \dfrac{0.50}{0.250} \)

\( = 2.0 \text{ mol/dm}^3 \)

Answer: 2.0 mol/dm3

Example 3 (Hard):

4.0 g of sodium hydroxide (Mr = 40) is dissolved to make 500 cm3 of solution. Calculate the concentration in mol/dm3.

▶️ Answer/Explanation

Step 1: Calculate moles

\( n = \dfrac{4.0}{40} = 0.10 \text{ mol} \)

Step 2: Convert volume

\( 500 \div 1000 = 0.50 \text{ dm}^3 \)

Step 3: Calculate concentration

\( c = \dfrac{0.10}{0.50} \)

\( = 0.20 \text{ mol/dm}^3 \)

Answer: 0.20 mol/dm3

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