IB DP Chemistry Topic 11.1 Uncertainties and errors in measurement and results SL Paper 1

Question

A student recorded the volume of a gas as \({\text{0.01450 d}}{{\text{m}}^{\text{3}}}\). How many significant figures are there in this value?

A.     3

B.     4

C.     5

D.     6

▶️Answer/Explanation

B

The first two zeroes in 0.01450 are insignificant because they are before the first non-zero digit, and the last zero is significant because it is after the first non-zero digit.

Hence, it has 4 significant figures.

Question

Which would be the best method to decrease the random uncertainty of a measurement in an acid-base titration?

A.     Repeat the titration

B.     Ensure your eye is at the same height as the meniscus when reading from the burette

C.     Use a different burette

D.     Use a different indicator for the titration

▶️Answer/Explanation

A

Random error or random uncertainty occurs due to chance. There is always some variability when a measurement is made. Random error may be caused by slight fluctuations in an instrument, the environment, or the way a measurement is read, that do not cause the same error every time. In order to address random error, scientists utilized replication. Replication is repeating a measurement many times and taking the average. Hence, repeating the titration would be the best method to decrease the random uncertainty of a measurement in an acid-base titration.

Question

Which are likely to be reduced when an experiment is repeated a number of times?

A.     Random errors

B.     Systematic errors

C.     Both random and systematic errors

D.     Neither random nor systematic errors

▶️Answer/Explanation

A

Random error occurs due to chance. There is always some variability when a measurement is made. Random error may be caused by slight fluctuations in an instrument, the environment, or the way a measurement is read, that do not cause the same error every time. In order to address random error, scientists utilized replication. Replication is repeating a measurement many times and taking the average.

Question

How many significant figures are there in 0.00370?

A.     2

B.     3

C.     5

D.     6

▶️Answer/Explanation

B

The first three zeroes in 0.00370 are insignificant because they are before the first non-zero digit, and the last zero is significant because it is after the first non-zero digit.

Hence, 0.00370 has 3 significant figures. 

Question

Density can be calculated by dividing mass by volume. \(0.20 \pm 0.02{\text{ g}}\) of a metal has a volume of \(0.050 \pm 0.005{\text{ c}}{{\text{m}}^{\text{3}}}\). How should its density be recorded using this data?

A.     \(4.0 \pm 0.025{\text{ g}}\,{\text{c}}{{\text{m}}^{ – 3}}\)

B.     \(4.0 \pm 0.8{\text{ g}}\,{\text{c}}{{\text{m}}^{ – 3}}\)

C.     \(4.00 \pm 0.025{\text{ g}}\,{\text{c}}{{\text{m}}^{ – 3}}\)

D.     \(4.00 \pm 0.8{\text{ g}}\,{\text{c}}{{\text{m}}^{ – 3}}\)

▶️Answer/Explanation

B

g

\(d=\frac{M}{V} = \frac{0.2}{0.050}\) = 4.0 g/. (d should be taken upto maximum of M and V, (i.e. maximum of 1 and 2 ) = 2 significant digits).

\(\frac{\Delta d}{d}=\pm (\frac{\Delta M}{M} + \frac{\Delta V}{V})\)  

\(\frac{\Delta d}{4}=\pm (\frac{0.02}{0.2} + \frac{0.005}{0.050})\) 

\(\Delta d\) = \(\pm0.8\) 

g/

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