IB DP Chemistry Topic 8.2 Properties of acids and bases SL Paper 1

Question

Which compound reacts with calcium oxide, CaO?

A.     \({{\text{K}}_{\text{2}}}{\text{O}}\)

B.     \({\text{N}}{{\text{a}}_{\text{2}}}{\text{O}}\)

C.     \({\text{S}}{{\text{O}}_{\text{2}}}\)

D.     MgO

▶️Answer/Explanation

C

Generally, metallic oxides are basic and non-metallic oxides are acidic in nature.

Calcium oxide is a basic oxide and it will react with the the only acidic oxide among the options, sulfur dioxide.

Question

Which gas in the atmosphere causes the pH of unpolluted rain to be approximately 6?

A.     Carbon dioxide

B.     Sulfur dioxide

C.     Oxygen

D.     Nitrogen

▶️Answer/Explanation

A

 Presence of \({\text{C}}{{\text{O}}_{\text{2}}}\) in the air causes pH of unpolluted rain water to be approximately 6 in many parts of the world.

Question

What occurs when solid sodium hydrogen carbonate reacts with aqueous sulfuric acid? 

A. Bubbles of sulfur dioxide form. 

B. Bubbles of both hydrogen and carbon dioxide form. 

C. Bubbles of hydrogen form. 

D. Bubbles of carbon dioxide form.

▶️Answer/Explanation

D

H2SO4 + 2 NaHCO3 → Na2SO4 + 2 CO2+ 2 H2O

Bubbles of carbon dioxide forms.

Question

A student carried out a titration to determine the concentration of an acid and found that his value had good precision but poor accuracy. Which process explains this outcome?

A. Consistently overshooting the volume of solution from the burette into the flask.

B. Collection of insufficient titration data.

C. Reading the meniscus in the burette at a different angle each time.

D. Forgetting to rinse the flask after one of the titrations.

▶️Answer/Explanation

A

The accuracy of titration requires precise measurement of the volume of materials in use. But markings on a burette can be easily misread. One way to misread the volume is by looking at the measurement on an angle. From above, it can seem like the volume is lower, while from below, the apparent volume looks higher. Another source of measurement error is looking at the wrong spot. A solution forms a concave curve and the bottom of the curve is used to measure the volume. If the reading is taken from the higher sections of the curve, the volume measurement will be in error.

The end point of a titration is when the reaction between the two solutions has stopped. Indicators, which change color to indicate when the reaction has stopped, do not change instantly. In the case of acid-base titration, the indicator may first lighten in color before changing completely. Also, each individual perceives color slightly differently, which affects the outcome of the experiment. If the color has changed slightly, too much of the titrant, which comes from the burette, can be introduced into the solution, overshooting results.

Here, precision is good but accuracy is poor which means the student is overshooting the volume of solution from the burette into the flask.

Question

What are the products of the reaction between sulfuric acid and sodium hydrogen carbonate?

A.     NaSO4 + H2O + CO2

B.     Na2SO4 + CO2

C.     Na2SO4 + H2O + CO2

D.     NaSO4 + H2CO3

▶️Answer/Explanation

C

H2SO4 + 2 NaHCO3 → Na2SO4 + 2 CO2+ 2 H2O

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